Oscillations in an array of bistable microelectrodes coupled through a globally conserved quantity.

Chaos

Institut de Chimie de Strasbourg, UMR7177, CNRS-Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg, France.

Published: April 2018

The dynamical behavior of an array of microelectrodes is investigated under controlled current conditions during CO electrooxidation, a bistable electrochemical reaction with an S-shaped negative differential resistance (S-NDR) current-potential curve. Under these conditions, the total current constitutes a globally conserved quantity, thus coupling all microelectrodes globally. Upon increasing the total current, the microelectrodes activate one by one, with a single microelectrode being on its intermediate S-NDR current branch and the other ones being either on their passive or their active branches. When a few coupled microelectrodes are activated, the electrochemical system exhibits spontaneous potential oscillations. Mathematical analysis shows that oscillations arise already in a two group approximation of the dynamics, the two groups consisting of 1 electrode and n - 1 electrodes with n ≥ 3, respectively, with each group being described by a single evolution equation. In this minimal representation, oscillations occur when the single electrode is on the intermediate branch and the larger group is on the active branch.

Download full-text PDF

Source
http://dx.doi.org/10.1063/1.5022475DOI Listing

Publication Analysis

Top Keywords

globally conserved
8
conserved quantity
8
total current
8
microelectrodes
5
oscillations
4
oscillations array
4
array bistable
4
bistable microelectrodes
4
microelectrodes coupled
4
coupled globally
4

Similar Publications

As one of China's most treasured traditional flowers, Rhododendron Subgen. Hymenanthes is renowned worldwide for its evergreen foliage, vibrant flowers, and significant ornamental, landscaping, and economic value. However, climate change poses a serious threat to its future, leading to population declines and endangerment of some species.

View Article and Find Full Text PDF

Ex situ conservation of plant genetic resources (PGR) plays a crucial role in sustainable growth and development, as highlighted by the Global Strategy for Plant Conservation (GSPC). Seed genebanks, a key component of ex situ conservation, have been instrumental in preserving plant diversity. However, challenges arise with the conservation of non-orthodox (recalcitrant and intermediate) seeds and vegetative tissues, which are not amenable to storage in traditional genebanks at temperatures of -20°C.

View Article and Find Full Text PDF

The biodiversity of ice-free Antarctica database.

Ecology

January 2025

Securing Antarctica's Environmental Future, School of Biological Sciences, Monash University, Melbourne, Victoria, Australia.

Antarctica is one of Earth's most untouched, inhospitable, and poorly known regions. Although knowledge of its biodiversity has increased over recent decades, a diverse, wide-ranging, and spatially explicit compilation of the biodiversity that inhabits Antarctica's permanently ice-free areas is unavailable. This absence hinders both Antarctic biodiversity research and the integration of Antarctica in global biodiversity-related studies.

View Article and Find Full Text PDF

On August 24, 2023, Japan controversially decided to discharge nuclear wastewater from the Fukushima Daiichi Nuclear Power Plant into the ocean, initiating intense domestic and global debates. This study employs a mixed-method approach, integrating quantitative evolutionary game theory and qualitative data analysis to explore the strategic dynamics among Japan, other nations, and the Japan Fisheries Association regarding this decision. The data includes international environmental reports and economic statistics, served as the basis for simulating decision-making processes under various legal, economic, and environmental pressures.

View Article and Find Full Text PDF

This review discusses the chemical properties, synthesis and detection, and biological functions of a molecular group of cis-2-unsaturated fatty acids, containing fatty acid carbon chains of various lengths and cis double-bond configurations, known as the diffusible signaling factor family (DSFF). Early postulation of the conserved nature of the DSFF among Gram-negative bacteria have now been challenged by the latest evidences that unraveled their presence in a various other distinct microorganisms. Over the last decade, a significant depth and breadth of understanding has been made on the multifaceted functions of DSFFs among bacteria, and their interactions with evolutionarily divergent fungi, plants insects and small animals.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!