A stabilizer called 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl acrylate (GM) was mixed in acrylonitrile butadiene styrene (ABS) with the same amount of 9-bis(octadecyloxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane (DSPDP), octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate (Irganox 1076) and tris(3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate (Irganox 3114) to investigate the influence of additives on the antiaging effect of ABS in oven aging or repeated extrusion aging. It was found that the ABS doped with the GM stabilizer showed a better yellowing resistance and thermal stability than the ABS doped with other antioxidants. Owing to the fact that the stabilizer can act on the free radicals before it has been peroxidized, it could trap the free radicals as a consequence of directly blocking the oxidation process of the active species, thus solving the problem of oxidative degradation of the materials from the source. This work provides guidance for improving thermal stability of ABS, indicating a promising potential for industrial application.
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http://dx.doi.org/10.3390/polym12010046 | DOI Listing |
Polymers (Basel)
December 2024
Metallurgical and Materials Engineering, Karadeniz Technical University, 61080 Trabzon, Turkey.
The introduction of 3D printing technology has broadened manufacturing possibilities, allowing the production of complex cellular geometries, including auxetic and curved plane structures, beyond the standard honeycomb patterns in sandwich composite materials. In this study, the effects of cell design parameters, such as cell geometry (honeycomb and auxetic) and cell size (cell thickness and width), are examined on acrylonitrile butadiene styrene (ABS) core materials produced using fusion deposition modeling (FDM). They are produced as a result of the epoxy bonding of carbon epoxy prepreg composite materials to the surfaces of core materials.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Polymer Extrusion Lab, The University of Texas at El Paso, El Paso, TX 79968, USA.
In the work presented here, we explore the upcycling of polyethylene terephthalate (PET) that was derived from water bottles. The material was granulated and extruded into a filament compatible with fused filament fabrication (FFF) additive manufacturing platforms. Three iterations of PET combined with a thermoplastic elastomer, styrene ethylene butylene styrene with a maleic anhydride graft (SEBS-g-MA), were made with 5, 10, and 20% by mass elastomer content.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Faculty of Mechatronics, Armament and Aerospace, Military University of Technology, 2 Gen. S. Kaliskiego Street, 00-908 Warsaw, Poland.
Advances in the development of additive manufacturing materials (AM) and the low availability of studies on the impact response of AM specimens are the main reasons for this paper. Therefore, the influence of building orientation (vertical and horizontal) and the angle of the raster (15°/-75°, 30°/-60°, 45°/-45°, and 0°/90°) on the tensile and impact strength of AM specimens was investigated. The polylactic acid (PLA)-PolyMax, Mediflex and acrylonitrile-butadiene-styrene (ABS) filaments were chosen to provide a comprehensive characterization of AM materials with versatile mechanical properties.
View Article and Find Full Text PDFMar Pollut Bull
January 2025
Institut des sciences de la mer, Université du Québec à Rimouski, Rimouski, Québec G5L 3A1, Canada. Electronic address:
Microplastic contamination in the St. Lawrence River and Estuary (SLRE), Canada, poses potential risks to aquatic species. However, limited understanding of microplastic contamination in benthic fish, potentially more vulnerable than pelagic species, impedes effective risk assessment in this crucial ecosystem.
View Article and Find Full Text PDFSci Rep
January 2025
Hydrobiology Lab, Water Pollution Research Department, National Research Centre, Dokki, Giza, 12622, Egypt.
Carbon black (CB) as rubber reinforcement has raised environmental concerns regarding this traditional petroleum-based filler, which is less susceptible to biodegradability. Although it has great reinforcing properties, the production technique is no longer sustainable, and its cost increases regularly. For these reasons, it is wise to look for sustainable replacement materials.
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