Organic matter removal from mother liquor of gas field wastewater by electro-Fenton process with the addition of HO: effect of initial pH.

R Soc Open Sci

College of Architecture and Environment, Sichuan University, Chengdu 610065, People's Republic of China.

Published: December 2019

The electro-Fenton (EF) process was applied to treat mother liquor of gas field wastewater (ML-GFW). The Fe-Fe electrodes were used and HO was added to the EF system. Effect of initial pH on chemical oxygen demand (COD) removal efficiency, specific electrical energy consumption (SEEC), specific electrode plate consumption (SEPC) and organic matter removal mechanism was investigated. The results showed that COD removal efficiency reached the maximum (71.9%) at initial pH of 3 after reaction for 3 h. Besides, considering with the SEEC and SEPC, pH of 3 was also the best choice, at which SEEC was 4.7 kW h kg , SEPC was 0.82 kgFe kg . Organic matter removal was achieved by two ways: oxidation and flocculation, and oxidation played a major role. With the analysis of GC-MS, the possible degradation pathways of the representative contaminants in the ML-GFW were given.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6936291PMC
http://dx.doi.org/10.1098/rsos.191304DOI Listing

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