In this study, a plasma in a liquid process (PiLP) was used to facilely precipitate bimetallic nanoparticles composed of Ni and Co elements on the surface of activated carbon. The physicochemical and electrochemical properties of the fabricated composites were evaluated to examine the potential of supercapacitors as electrode materials. Nickel and cobalt ions in the aqueous reactant solution were uniformly precipitated on the AC surface as spherical nanoparticles with a size of about 100 nm by PiLP reaction. The composition of nanoparticles was determined by the molar ratio of nickel and cobalt precursors and precipitated in the form of bimetallic oxide. The electrical conductivity and specific capacitance were increased by Ni-Co bimetallic oxide nanoparticles precipitated on the AC surface. In addition, the electrochemical performance was improved by stable cycling stability and resistance reduction and showed the best performance when the molar ratios of Ni and Co precursors were the same.
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http://dx.doi.org/10.3390/nano10010061 | DOI Listing |
Int J Biol Macromol
December 2024
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China. Electronic address:
The conversion of abundant lignin was of great significance for the utilization of biomass resources. In this study, lignin sulfonate (LS) was selected as a carbon-based support, which was successfully introduced into the NiCo-MOF structure. A series of lignin and MOF hybrid catalysts (NiCo-MOF-LS) with varying metal ratios of Ni and Co were synthesized via the hydrothermal method.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489, Berlin, Germany.
Polymers (Basel)
November 2024
School of Instrument and Electronics, North University of China, Taiyuan 030051, China.
Toxics
November 2024
School of Environmental Science and Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China.
In this work, NiCoO was synthesized from bimetallic oxalate and utilized as a heterogeneous catalyst to active peroxymonosulfate (PMS) for the degradation of tetracycline (TC). The degradation efficiency of TC (30 mg/L) in the NiCoO + PMS system reached 92.4%, with NiCoO exhibiting satisfactory reusability, stability, and applicability.
View Article and Find Full Text PDFJ Mater Chem B
November 2024
Department of Emergency, Changhai Hospital, Naval Medical University, Shanghai 200433, China.
Conventional inorganic semiconductors are not suitable for acting as nanozymes or sonosensitizers for therapeutic nanomedicine owing to the lack of excellent biocompatibility. Biocompatible carbon dots (CDs) exhibit a variety of biological activities due to their adjustable size and surface chemical modification; however, the simultaneous sonodynamic activity and multiple enzyme-mimicking catalytic activity of a single CD have not been reported. Herein, we report the development of bimetallic doped CDs as a high-efficiency nanozyme and sonosensitizer for enhanced sonodynamic therapy (SDT) and nanocatalytic therapy (NCT).
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