The reaction of organobismuth precursors with trityl--phosphinic acid in varying reaction conditions afforded colorless crystals, whose single crystal X-ray characterization revealed the formation of monomer {(PhBi)[(PhC)(H)PO]}·/(CHCN)./HO () and butterfly shaped tetranuclear cluster Bi(μ-O)[(PhC)(H)(PO)]·2CHCl·/CHCN.2HO (). The reaction of titanium isopropoxide with two different phosphinic acids trityl--phosphinic acid and P(O)(OH) led to isolation of cubane type octahedral complex {Ti(μ-O)(μ-OH)[(PhC)(H)PO]}[3CH] () and hexanuclear complex Ti(μ-PO)(μ-O)(μ-OH)·4CHCN·4HO () respectively.
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