Localized Electrical Induction Heating for Highly Efficient Synthesis and Regeneration of Metal-Organic Frameworks.

Based on carbon fibers (CFs) delivered localized electrical induction heat, a novel electrical induction framework synthesis (EIFS) strategy has been developed to in-situ grow versatile metal-organic frameworks (MOFs) on CFs, resulting in the production of a set of MOF-coated CF (MOF@CF) fibers. Detailed studies on the production of UiO-66-NH@CFs indicate that the use of EIFS leads to dramatically accelerated MOF growth at dozen times higher reaction rate than that of the conventional solvothermal reaction. By periodically switching anodes during EIFS reactions, uniform MOF@CF fibers with well-controlled MOF loadings have been achieved depending on the reaction conditions. Mediated by the embedded CFs in the resulting MOF@CFs, MOF@CFs exhibit well-regulated electrical induction heating capacities depending on MOF loadings and the applied voltages. Driven by such localized heat, up to 100% of the adsorbed CO in UiO-66-NH@CF can be rapidly released, demonstrating an electrical induction framework regeneration (EIFR) process for highly efficient regeneration of MOFs. As CFs enable to rapidly deliver localized electrical induction with over 90% of electrothermal conversion efficiency and at rather low operation voltage, currently developed EIFS and EIFR process provide a highly efficient, low-energy, low operation cost, and safe way to highly efficient synthesis and regeneration of MOF materials.