The femtosecond laser machining of fused silica in air and liquids is studied. The ablation threshold of fused silica is reduced from 2.22 to ${1.02}\;{{\rm J/cm}^2}$1.02J/cm. In order to explore the ablation mechanism fabricated in a liquid medium, the absorption characteristics of water and alcohol are studied. It is found that alcohol could absorb more laser energy than water. By analyzing the variation trend of laser-induced electron density based on an ionization model, we find that alcohol requires lower laser energy to reach the electron density standard and form plasma than water and fused silica. Besides, we observe that a laser will induce bubbles in liquids after the formation of plasma, and the bubbles in alcohol will cause stronger impact pressure to the surface of fused silica than those in water. Therefore, the mechanism of threshold reduction should be owed to the assistance of liquids with different characteristics.
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http://dx.doi.org/10.1364/AO.58.009027 | DOI Listing |
Int J Mol Sci
December 2024
Department of Chemistry, College of Science, Taif University, Taif P.O. Box 11099, Saudi Arabia.
In this study, new monolithic poly(9-anthracenylmethyl methacrylate-co-trimethylolpropane trimethacrylate (TRIM) columns, referred as ANM monoliths were prepared, for the first time, and were used for the separation media for biomolecules and proteomics analysis by nano-liquid chromatography (nano-LC). Monolithic columns were prepared by in situ polymerization of 9-anthracenylmethyl methacrylate (ANM) and trimethylolpropane trimethacrylate (TRIM) in a fused silica capillary column of 100 µm ID. Polymerization solution was optimized in relation to monomer and porogenic solvent.
View Article and Find Full Text PDFLangmuir
January 2025
Institute of Physics, Czech Academy of Sciences, Na Slovance 2, 182 21 Prague 8, Czech Republic.
Black aluminum is a material characterized by high surface porosity due to columnar growth and exhibits unique optical properties that make it attractive for applications such as light trapping, infrared detection, and passive thermal radiation cooling. In this study, we correlate the structural and optical properties of black aluminum by comparing it with conventional reflective aluminum layers. These layers of varying thicknesses were deposited on fused silica substrates, and their optical properties were analyzed.
View Article and Find Full Text PDFElectrophoresis
December 2024
Chinese Academy of Inspection and Quarantine, Beijing, China.
An analytical method for identifying the chemical constituents in the Chinese herbal combination Jiuwei decoction was established using capillary electrophoresis coupled with quadrupole time-of-flight mass spectrometry. Nine herbs were extracted with a 60:40 (v/v) ethanol/water solution to prepare the Jiuwei decoction. Electrophoretic separation was carried out using a 50 µm i.
View Article and Find Full Text PDFJ Chromatogr A
January 2025
Restek Corporation, 110 Benner Circle, Bellefonte, PA, 16823, USA. Electronic address:
The chemical structure of nine imidazolium sulfonate and triflimide zwitterionic liquids (ZILs) were systematically tuned to increase their thermal stability for gas chromatography (GC) separations. Substituents for imidazolium and 2-phenylimidazolium cation systems, comprised of alkyl, benzyl, and oligoether groups of varying chain lengths, were studied as stationary phases in GC. Propanesulfonate, ethanesulfonate, and propanetriflimide anions were examined to understand the effect of linker length and nucleophilicity on ZIL thermal stability.
View Article and Find Full Text PDFAppl Phys Lett
January 2024
Communications Technology Laboratory, National Institute of Standards and Technology, 325 Broadway, Boulder, Colorado 80305, USA.
Fused silica has become an interesting alternative to silicon for millimeter-wave (mmWave) applications. Unfortunately, there are a few reports on the measurement of fused silica's permittivity above 110 GHz that use electrical rather than optical methods. Given that mmWave applications use electrical circuits, additional electrical data would be useful to industry.
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