Metal halide perovskite solar cells (PSCs), with their exceptional properties, show promise as photoelectric converters. However, defects in the perovskite layer, particularly at the grain boundaries (GBs), seriously restrict the performance and stability of PSCs. Now, a simple post-treatment procedure involves applying 2-aminoterephthalic acid to the perovskite to produce efficient and stable PSCs. By optimizing the post-treatment conditions, we created a device that achieved a remarkable power conversion efficiency (PCE) of 21.09 % and demonstrated improved stability. This improvement was attributed to the fact that the 2-aminoterephthalic acid acted as a cross-linking agent that inhibited the migration of ions and passivated the trap states at GBs. These findings provide a potential strategy for designing efficient and stable PSCs regarding the aspects of defect passivation and crystal growth.
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http://dx.doi.org/10.1002/anie.201915422 | DOI Listing |
Dalton Trans
December 2024
Department of Applied Chemistry, National Chi Nan University, Nantou 545, Taiwan.
Anal Chem
December 2024
School of Chemistry, South China Normal University, Guangzhou 510006, China.
Vanadate has become an important indicator for environmental testing due to its high toxicity, mobility, and difficulty in degradation. In addition, depending on its dynamic aggregation, analyzing vanadate is not a single content test; it needs further morphological analysis. Previous research has tended to construct a single functional platform with complicated procedures and expensive equipment, making it difficult to obtain a comprehensive picture of vanadate in a short time.
View Article and Find Full Text PDFTalanta
March 2025
College of Chemistry and Chemical Engineering, Qingdao Application Technology Innovation Center of Photoelectric Biosensing for Clinical Diagnosis and Treatment, Shandong Sino-Japanese Center for Collaborative Research of Carbon Nanomaterials, Instrumental Analysis Center of Qingdao University, Qingdao University, Qingdao, 266071, China. Electronic address:
The functionalized architecture within the nanoreactor could dramatically change the electron transport and reaction efficiency of ECL during electrochemical processes. Here, we've devised a novel mixed-ligand strategy that combines co-reaction accelerator and morphologic regulator onto the same metal node. This innovative approach effectively addressed the critical issue that some co-reactants cannot be covalently linked due to their special states, while enhancing the stability and electroactivity of MOFs nanoreactors.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
February 2025
College of Chemistry, Institute of Analytical Chemistry for Life Science, Zhengzhou University, Zhengzhou 450001, PR China. Electronic address:
Some metal ions, with inner enzyme-like catalytic activity, could be doped into lanthanide coordination polymers (Ln CPs) through coordination, which has been proved as a facile strategy to prepare the luminescent nanozymes. In this study, Cu-doped Ln CPs with laccase-mimic activity and double luminescence were rationally designed and synthesized by self-assembly of guanine monophosphate (GMP), 2-aminoterephthalic acid (ATA), Cu and Tb in buffer solution at room temperature. The obtained probes Tb/Cu-GMP/ATA CPs not only emitted green fluorescence of Tb and blue fluorescence of ATA simultaneously under irradiation at the same wavelength, but also processed enhanced laccase-like activity for catalyzing the oxidation of phenolic substrates.
View Article and Find Full Text PDFSci Rep
October 2024
Centre for Nano and Material Sciences, Jain (Deemed-to-be University), Jain Global Campus, Kanakapura, Bangalore, Karnataka, 562112, India.
The development of photocatalysts must be meticulous, especially when they are designed to degrade hazardous dyes that cause mutagenesis and carcinogenesis. In this meticulous approach, Ni-based metal-organic frameworks with different ligands, including terephthalic acid (NTP), 2-aminoterephthalic acid (NATP), and their composite with g-CN (NTP/GCN, and NATP/GCN) have been synthesized using hydrothermal method. Structural analysis by XRD and ATR-IR revealed synergistic properties due to robust chemical interactions between the NATP-MOFs and GCN systems.
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