Visible-lightdriven C-TiO nanocomposites were prepared via a simple calcination and acid etching process. The C-TiO nanocomposites were characterized by X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction, transmission electron microscopy, and high-resolution TEM. The results showed that TiO nanoparticles were combined with a porous carbon layer through surface C-O groups, which facilitates the strong interface interaction. The interface combination of nano-TiO and carbon material increases the specific surface area of nano-TiO, widens the range of light response, and improves the efficiency of light-induced electron migration. The visible-light photocatalytic activity of the prepared photocatalyst was evaluated by the decomposition of tetracycline aqueous solution. Compared with that of pure TiO, the photocatalytic activity of C-TiO nanocomposites was significantly improved. Furthermore, a possible photocatalytic mechanism was also tentatively proposed. This work can promote the development of active photocatalysts under solar light for the photodegradation of environmental pollutants.
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http://dx.doi.org/10.1021/acsomega.9b02411 | DOI Listing |
Adv Sci (Weinh)
December 2024
Tongji School of Pharmacy, Huazhong University of Science and Technology, Wuhan, 430030, P. R. China.
The monitoring and removal of environmental pollutants are vital for the sustainable development of society. Herein, a novel nanocomposite combining silicon nanoparticles and carbon-doped titania, C-TiO/SiNPs, is designed as a fluorescence probe and visible-light photocatalyst to simultaneously monitor and degrade oxytetracycline (OTC). C-TiO/SiNPs emit blue fluorescence, which can be quenched by OTC through inner filter effect.
View Article and Find Full Text PDFAdv Mater
January 2024
School of Engineering, Brown University, Providence, RI, 02912, USA.
The combined effects of compact TiO (c-TiO ) electron-transport layer (ETL) are investigated without and with mesoscopic TiO (m-TiO ) on top, and without and with an iodine-terminated silane self-assembled monolayer (SAM), on the mechanical behavior, opto-electronic properties, photovoltaic (PV) performance, and operational-stability of solar cells based on metal-halide perovskites (MHPs). The interfacial toughness increases almost threefold in going from c-TiO without SAM to m-TiO with SAM. This is attributed to the synergistic effect of the m-TiO /MHP nanocomposite at the interface and the enhanced adhesion afforded by the iodine-terminated silane SAM.
View Article and Find Full Text PDFIndian J Microbiol
June 2023
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Pattimura, Ambon, Maluku 97233 Indonesia.
Unlabelled: Crop destruction organisms are an essential factor hindering cocoa plants' production yield. It is the biggest problem for cocoa farmers to resolve and reduce the impact of the fungus on cocoa pods. Herein, this study presents the optimization of inorganic pesticides based on nano-carbon self-doped TiO (C/TiO) nanocomposites capable of disinfecting broad-spectrum microorganisms for the practical application of photodisinfection technology.
View Article and Find Full Text PDFInt J Biol Macromol
June 2023
Department of Environmental Engineering and Management, Chaoyang University of Technology, Taichung, Taiwan. Electronic address:
A nanohybrid prepared from the lignocellulosic residue is a feasible approach to synthesize blue light emitting fluorescent doped TiO quantum dot nanocomposite (C-TiO QDs) by microwave techniques using Mandarin orange (Citrus reticulata) peel powder with titanium isopropoxide precursors. With a greater orange peel colloidal medium, the structure of the TiO-NPs changed from a mixture of rutile and anatase phases to exclusively the anatase phase. The optical and morphological properties of as-prepared C-TiO QDs were characterized by HR-TEM, XRD, FT-IR, UV-visible, PL spectra, DLS, and Zeta potential techniques.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
May 2023
Research Department of Chemistry, Kuriakose Elias College, Mannanam, Kottayam, Kerala, 686561, India.
The existence of antibiotics in aquatic streams destroys water quality and thereby poses serious ecological hitches. Photocatalysis involving nanosemiconductors is an environmentally benign technique for the mineralization of antibiotics. Herein, we prepared a new visible light-sensitive photocatalyst, zeolite Y-supported carbon-doped TiO nanocomposite (zeolite Y-c-TiO), for the elimination of cefazolin antibiotic in wastewater systems.
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