The recent discovery of the interfacial superconductivity (SC) of the BiTe/FeTe heterostructure has attracted extensive studies due to its potential as a novel platform for trapping and controlling Majorana fermions. Here we present studies of another topological insulator (TI)/FeTe heterostructure, SbTe/FeTe, which also has an interfacial 2-dimensional SC. The results of transport measurements support that reduction of the excess Fe concentration of the FeTe layer not only increases the fluctuation of its antiferromagnetic (AFM) order but also enhances the quality of the SC of this heterostructure system. On the other hand, the interfacial SC of this heterostructure was found to have a wider-ranging TI-layer thickness dependence than that of the BiTe/FeTe heterostructure, which is believed to be attributed to the much higher bulk conductivity of SbTe that enhances indirect coupling between its top and bottom topological surface states (TSSs). Our results provide evidence of the interplay among the AFM order, itinerant carries from the TSSs, and the induced interfacial SC of the TI/FeTe heterostructure system.
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http://dx.doi.org/10.1073/pnas.1914534117 | DOI Listing |
Adv Mater
January 2025
Faculty of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Sagamihara, Kanagawa, 252-5258, Japan.
Twistronics, a novel engineering approach involving the alignment of van der Waals (vdW) integrated two-dimensional materials at specific angles, has recently attracted significant attention. Novel nontrivial phenomena have been demonstrated in twisted vdW junctions (the so-called magic angle), such as unconventional superconductivity, topological phases, and magnetism. However, there have been only few reports on integrated vdW layers with large twist angles θ, such as twisted interfacial Josephson junctions using high-temperature superconductors.
View Article and Find Full Text PDFSmall
January 2025
School of Chemistry, South China Normal University, Guangzhou, 510006, P. R. China.
Intrinsic low conductivity, poor structural stability, and narrow interlayer spacing limit the development of MnO in sodium-ion (Na) supercapacitors. This work constructs the hollow cubic Mn-PBA precursor through an ion-exchange process to in situ obtain a hollow cubic H-Ni-MnO composite with Ni doping and oxygen vacancies (O) via a self-oxidation strategy. Experiments and theoretical calculations show that the hollow nanostructure and the expanding interlayer spacing induced by Ni doping are beneficial for exposing more reactive sites, synergistically manipulating the Na transport pathways.
View Article and Find Full Text PDFAdv Mater
January 2025
Institute for Superconducting & Electronic Materials (ISEM), Faculty of Engineering and Information Sciences, University of Wollongong, Innovation Campus, Squires Way, North Wollongong, NSW, 2500, Australia.
Adv Mater
December 2024
Department of Physics and Texas Center for Superconductivity at the University of Houston (TcSUH), University of Houston, Houston, TX, 77204, USA.
Angew Chem Int Ed Engl
December 2024
State Key Laboratory of Reliability and Intelligence of Electrical Equipment, School of Materials Science and Engineering, Hebei University of Technology, Tianjin, 300401, China.
Low-concentration electrolytes (LCEs) have attracted great attention due to their cost effectiveness and low viscosity, but suffer undesired organic-rich interfacial chemistry and poor oxidative stability. Herein, a unique latent solvent, 1,2-dibutoxyethane (DBE), is proposed to manipulate the anion-reinforced solvation sheath and construct a robust inorganic-rich interface in a 0.5 M electrolyte.
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