In order to analyze the sources and factors influencing heavy metal pollution in industrial cities, 62 surface layer (0-20 cm) soil samples were collected in Baoji City for analysis using inductively coupled plasma mass spectrometry (ICP-MS). Cd, As, Cu, Pb, Zn, Cr, Mn, and Ni were detected in the samples. Based on geostatistical methods and geo-detector models, the soil heavy metal pollution load index (PLI) was selected as the best indicator of factors affecting heavy metal pollution. The Unmix 6.0 receptor model was also used to analyze the heavy metal source. The results showed that:① The average concentrations of Cd, Pb, Cu, Zn, As, Cr, Mn, and Ni in the surface soils of Baoji City were 0.77 mg·kg, 16.75 mg·kg, 40.52 mg·kg, 261 mg·kg, 17.03 mg·kg, 49.18 mg·kg, 331 mg·kg, and 30.52 mg·kg, respectively. These values exceeded the national secondary standard for Cd and Zn, which were 8.2 and 3.8 times more abundant, respectively, than in the background soils of Shaanxi Province, indicating that urban soils are seriously polluted with Cd and Zn. The average concentrations of Cu, As, and Ni also exceeded the background levels; ② The total pollution load index (PLI) for heavy metals in the surface soils of Baoji City was 1.36, which indicated mild levels of pollution, as analyzed using a geo-detector. Soil texture and distance to the city's railway had the strongest explanatory power for the distribution of pollutants (=0.040 and 0.026, respectively, with a combined explanatory power of 0.099); ③ Cd, Cu, and As mainly derive from "artificial sources" associated with industrial and agricultural activities, and Zn and Ni derive from traffic emissions. Cr, Pb, and Mn mainly derive from "mixed sources". Overall, the main source of heavy metals in the surface soils of the study area was classified as "mixed source" and soils were classified as having a mild level of pollution. These results provide scientific support for the prevention and control of heavy metal pollution in the soils of Baoji City.
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http://dx.doi.org/10.13227/j.hjkx.201811114 | DOI Listing |
Mater Horiz
January 2025
Institute of Biomass Engineering, Key Laboratory of Energy Plants Resource and Utilization, Ministry of Agriculture and Rural Affairs, South China Agricultural University, Guangzhou, 510642, China.
Conversion of nitrogen (N) to ammonia (NH) is a significant process that occurs in environment and in the field of chemistry, but the traditional NH synthesis method requires high energy and pollutes the environment. In this work, the charge, orbital and spin order of the single-atom Fe loaded on heteroatom (X) doped-MoCS (X = B, N, O, F, P and Se) and its synergistic effect on electrochemical nitrogen reduction reaction (eNRR) were investigated using well-defined density functional theory (DFT) calculations. Results revealed that the X-element modified the charge loss capability of Fe atoms and thereby introduced a net spin through heteroatom doping, resulting in the magnetic moment modulation of Fe.
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January 2025
Department of Food Science and Biotechnology, Gachon University 1342 Seongnamdaero Sujeong-gu Seongnam-si 13120 Republic of Korea
This study focuses on the synthesis, characterization, and evaluation of the photocatalytic efficiency of bismuth-based metal-organic frameworks (Bi-MOFs) and their derivatives, specifically Ag/Bi-MOF and NH /Ag/Bi-MOF, in the degradation of tetracycline (TC) and sulfamethoxazole (SMX) under visible light irradiation. Bi-MOFs are promising photocatalysts due to their large surface area, tunable porosity, and unique electronic properties that are favorable for visible light absorption. In this study, Bi-MOFs were synthesized using a solvothermal method, with the incorporation of silver (Ag) and ammonium (NH ) ions to enhance their photocatalytic performance.
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January 2025
Department of Botany, Division of Science and Technology, University of Education, Lahore, Punjab, Pakistan.
Anthropogenic activities such as industrial pollution of water bodies possess threat to floras leading to extinction and endangerment. This study investigates the impact of industrial pollution on vegetation along River Chenab and its associated drains. Rivers and channels transporting industrial effluents have been determined to be significantly contaminated.
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January 2025
Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran.
Co-pyrolysis is an efficient approach for municipal sewage sludge (SS) treatment, facilitating the production of biochar and promoting the stabilization and removal of heavy metals, particularly when combined with chlorinated materials. This study explores the impact of pyrolysis temperatures (400 °C and 600 °C) and chlorinated additives (polyvinyl chloride (PVC) as an organic chloride source and ferric chloride (FeCl) as an inorganic chloride source) at 10% and 20% concentrations, on the yield, chemical speciation, leachability, and ecological risks of arsenic (As), chromium (Cr), and zinc (Zn) in biochar derived from SS. The results revealed that increasing the pyrolysis temperature from 400 to 600 °C significantly reduced biochar yield due to enhanced volatilization of organic components, as well as the removal of heavy metals in interaction with chlorinated materials.
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January 2025
Nanning Center for Disease Control and Prevention, Nanning, 530021, Guangxi, China.
Nowadays rice has become one of the world's staple foods. Rice in southern China is also a staple food for everyone, however, with the development of China's industrialization model, many industrial areas may be contaminated by heavy metals, leading to contamination of the agricultural areas. With the development of recent years, Nanning has become a heavily industrial development area, and rice is also a favourite staple food.
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