Ruthenium(II) alkylidene complexes such as the Grubbs' 1st and 2nd generation catalysts undergo a ligand substitution with 2,2'-bipyridine, which readily leads to the common photoredox catalyst Ru(bpy) . The application of this catalyst transformation in sequential olefin metathesis/photoredox catalysis is demonstrated by way of ring-closing metathesis (RCM)/photoredox ATRA reactions.
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| http://dx.doi.org/10.1002/chem.201905694 | DOI Listing |
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