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Second-Generation -Phenolsulfonic Acid-Formaldehyde Resin as a Catalyst for Continuous-Flow Esterification. | LitMetric

A second-generation -phenolsulfonic acid-formaldehyde resin (PAFR II) catalyst was prepared by condensation polymerization of sodium -phenolsulfonate and paraformaldehyde in an aqueous HSO solution. This reusable, robust acid resin catalyst was improved in both catalytic activity and stability, maintaining the characteristics of the previous generation catalyst (-phenolsulfonic acid-formaldehyde resin). PAFR II was applied in the batchwise and continuous-flow direct esterification without water removal and provided higher product yields in continuous-flow esterification than any other commercial ion-exchanged acid catalyst tested.

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http://dx.doi.org/10.1021/acs.orglett.9b04084DOI Listing

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