Experimental investigations and numerical modelling of in-situ reactive caps for PAH contaminated marine sediments.

J Hazard Mater

Department of Civil, Environmental, Land, Building Engineering and Chemistry, Polytechnic University of Bari, Via E. Orabona 4, 70125 Bari, Italy.

Published: April 2020

AI Article Synopsis

Article Abstract

The present study compared numerical modelling and experimental investigations to evaluate the effectiveness of in-situ reactive capping for marine sediments contaminated by polycyclic aromatic hydrocarbons (PAHs). As a case study, sediment samples from Mar Piccolo (Italy) were analyzed and experiments were undertaken using batch columns. Two types of capping amendments were tested: AquaGate® + 5 % of powdered activated carbon (AG PAC) and Organoclay Reactive Core Mat (OC RCM). The column tests were carried out for 20 days, obtaining a short-term PAH distribution for three cases analysed, which compared the application of the two caps with no intervention. In parallel, in order to evaluate the intervention long term efficacy, an ad-hoc multilayered model predicting PAH concentrations into the sediments and the overlying water column was developed and validated with the experimental results. Both capping systems considerably reduced PAH concentrations in the overlying water, with the highest performance seen in AG PAC for benzo[a]pyrene (99 %) and anthracene (72 %); results also confirmed in the model predictions. In addition, the numerical simulations indicated a good efficiency of both caps over time, obtaining PAH values below the threshold limit in the long term. Although further experiments need to be developed accounting for multiple contamination competitiveness.

Download full-text PDF

Source
http://dx.doi.org/10.1016/j.jhazmat.2019.121724DOI Listing

Publication Analysis

Top Keywords

experimental investigations
8
numerical modelling
8
in-situ reactive
8
marine sediments
8
long term
8
pah concentrations
8
overlying water
8
pah
5
investigations numerical
4
modelling in-situ
4

Similar Publications

Effects of combinations of the essential oils trans-anethole, thymol and carvacrol against larvae of the screwworm fly Cochliomyia hominivorax in vitro.

Vet Parasitol

January 2025

Laboratório de Quimioterapia Experimental em Parasitologia Veterinária (LQEPV), Universidade Federal Rural do Rio de Janeiro, Seropédica, Brazil; Departamento de Parasitologia Animal, Instituto de Medicina Veterinária, Universidade Federal Rural do Rio de Janeiro, Seropédica, Rio de Janeiro, Brazil.

This study investigated the combined effect of trans-anethole, carvacrol and thymol on third-instar larvae of C. hominivorax. For this experiment, third-stage larvae of C.

View Article and Find Full Text PDF

Meteoritic impacts on planetary surfaces deliver a significant amount of energy that can produce prebiotic organic compounds such as cyanides, which may be a key step to the formation of biomolecules. To study the chemical processes of impact-induced organic synthesis, we simulated the physicochemical processes of hypervelocity impacts (HVI) in experiments with both high-speed C projectiles and laser ablation. In the first approach, a C beam was accelerated to collide with ammonium nitrate (NHNO) to reproduce the shock process and plume generation of meteoritic impacts on nitrogen-rich planetary surfaces.

View Article and Find Full Text PDF

Dragonfly larvae rearing: experimental insights and best practices.

Environ Entomol

January 2025

Department of Biology and Ecology, Faculty of Science, University of Ostrava, Ostrava, Czech Republic.

Understanding and optimizing rearing conditions for dragonfly larvae is crucial for ecological research and conservation efforts, yet optimal rearing conditions and general rearing practices are lacking. In this study, we investigated the effect of temperature, amount of oxygen in water, presence of (artificial) plants, and age of eggs on hatchability, survival, and development of dragonfly larvae using the model species Sympetrum striolatum. We conducted three independent experiments and assessed variability between egg clutches of individual females, as well as the occurrence of cannibalism among larvae.

View Article and Find Full Text PDF

Pain is closely linked to alpha oscillations (8 < 13 Hz) which are thought to represent a supra-modal, top-down mediated gating mechanism that shapes sensory processing. Consequently, alpha oscillations might also shape the cerebral processing of nociceptive input and eventually the perception of pain. To test this mechanistic hypothesis, we designed a sham-controlled and double-blind electroencephalography (EEG)-based neurofeedback study.

View Article and Find Full Text PDF

Objective: This study aimed to evaluate the positive effects on anti-oxidation, anti-inflammation, and microbial composition optimization of diabetic mice using tussah (Antheraea pernyi) silk fibroin peptides (TSFP), providing the theoretical foundation for making the use of silk resources of A. pernyi and incorporating as a supplement into the hypoglycemic foods.

Method: The animal model of diabetes was established successfully.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!