High electrical conductivity and strong absorption of electromagnetic radiation in the terahertz (THz) frequency range by metallic 2D MXene TiCT make it a promising material for electromagnetic interference shielding, THz detectors, and transparent conducting electrodes. Here, we demonstrate that ultrafast optical pulses with wavelengths straddling the visible range (400 and 800 nm) induce transient broad-band THz transparency in the MXene that persists for nanoseconds. We demonstrate that optically induced transient THz transparency is independent of temperature from 95 to 290 K. This discovery opens new possibilities for development of switchable electromagnetic interference shielding materials and devices that can be rendered partially transparent on demand for transmitting THz signals, or for designing new THz devices such as sensitive optically gated detectors.
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http://dx.doi.org/10.1021/acs.nanolett.9b04404 | DOI Listing |
ACS Nano
January 2025
NanoScience Technology Center, Department of Materials Science and Engineering, Department of Chemistry, Renewable Energy and Chemical Transformation Cluster, The Stephen W. Hawking Center for Microgravity Research and Education, University of Central Florida, Orlando, Florida 32826, United States.
Advanced electromagnetic interference (EMI) shielding materials are in great demand because of the severe electromagnetic population problem caused by the explosive growth of advanced electronics. Besides superior EMI shielding properties, the mechanical strength of the shielding materials is also critical for some specific application scenarios (e.g.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 1, Singapore, 117585, Singapore.
Strong background interference signals from normal tissues have significantly compromised the sensitive fluorescence imaging of early disease tissues with exogenous probes in vivo, particularly for sensitive fluorescence imaging of early liver disease due to the liver's significant uptake and accumulation of exogenous nanoprobes, coupled with high tissue autofluorescence and deep tissue depth. As a proof-of-concept study, we herein report a near-infrared-II (NIR-II, 1.0-1.
View Article and Find Full Text PDFSci Rep
January 2025
Faculty of Mechanical and Electrical Engineering, Quzhou College of Technology, Quzhou, 324000, Zhejiang, China.
Integrating the Internet of Things (IoT) in smart grids has revolutionized the energy sector, enabling real-time data collection and efficient energy distribution. However, this integration also introduces significant security challenges, particularly data encryption. Traditional encryption algorithms used in IoT are vulnerable to various attacks, and the advent of quantum computing exacerbates these vulnerabilities.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Chemical Engineering, University of South Carolina, Columbia, South Carolina 29208, United States.
Rapid evolution of smart devices necessitates high-performance, lightweight materials for effective electromagnetic interference (EMI) shielding. TiCT MXene nanosheets are promising for such applications, yet the high solid content typically required for 3D-printable MXene inks limits their scalability and cost efficiency. In this study, we present an MXene-based ink with an ultralow solid content (0.
View Article and Find Full Text PDFMikrochim Acta
December 2024
Chemistry Institute, Federal University of Uberlândia, Uberlândia, MG, 38408-100, Brazil.
Babassu (Atallea sp.), a native palm tree from South America's Amazon produces bio-oil and biochar with significant potential for industrial applications. Babassu oil as a bio-based plasticizer is reported here for the first time to replace petrochemical alternatives in the production of conductive filaments for additive manufacturing purposes.
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