4D-printed materials are an emerging field of research because the physical structure of these novel materials respond to environmental changes. 3D printing techniques have been employed to print a base material with shape memory properties. Geometrical deformations can be observed once an external stimulus triggers the shape memory effect (SME) integrated into the material. The plasticizing effect is a well-known phenomenon where the microscopic polymer chain movements have been altered and reflected in different shape memory behaviour. It has been suggested that a 4D material with localized actuation behaviour can be fabricated by utilizing functionally graded layers made from different degrees of plasticizing. This study demonstrated that a novel 4D material can be fabricated from material extraction continuous printing technique with different loadings of poly(ethylene glycol) (PEG) plasticize, achieving localized thermal recovery. The results indicate that a plasticized functional layer is an effective technique for creating next generation 4D materials.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6904723PMC
http://dx.doi.org/10.1038/s41598-019-55298-1DOI Listing

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