Anisotropic small structures found throughout living nature have unique functionalities as seen by Gecko lizards. Here, we present a simple yet programmable method for fabricating anisotropic, submicrometer-sized bent pillar structures using photoreconfiguration of an azopolymer. A slant irradiation of a p-polarized light on the pillar structure of an azopolymer simply results in a bent pillar structure. By combining the field-gradient effect and directionality of photofluidization, control of the bending shape and the curvature is achieved. With the bent pillar patterned surface, anisotropic wetting and directional adhesion are demonstrated. Moreover, the bent pillar structures can be transferred to other polymers, highlighting the practical importance of this method. We believe that this pragmatic method to fabricate bent pillars can be used in a reliable manner for many applications requiring the systematic variation of a bent pillar structure.
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http://dx.doi.org/10.1021/acsami.9b19420 | DOI Listing |
Chem Mater
October 2024
Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain.
Herein, we report the first examples of supramolecular systems from bent-core-based pillar[]arenes through ionic bonds. These ionic materials have been prepared by the interaction of an amino-ended pillar[5]arene (P5N10) and three different carboxylic acids, including bent-core moieties. The bent-core units are based on ester, biphenyl, and azobenzene structures bearing two different flexible spacers between the carboxyl group and the central bent-core aromatic units.
View Article and Find Full Text PDFChem Sci
June 2024
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, IGCME, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, Sun Yat-Sen University Guangzhou 510275 P. R. China
Stepped spin crossover (SCO) complexes with three or more spin states have promising applications in high-order data storage, multi-switches and multi-sensors. Further synergy with other functionalities, such as luminescence and dielectric properties, will provide a good chance to develop novel multifunctional SCO materials. Here, a bent pillar ligand and luminescent pyrene guest are integrated into a three-dimensional (3D) Hofmann-type metal-organic framework (MOF) [Fe(dpoda){Au(CN)}]·pyrene (dpoda = 2,5-di-(pyridyl)-1,3,4-oxadiazole).
View Article and Find Full Text PDFSupport Care Cancer
November 2023
Department of Medical Oncology, Netherlands Cancer Institute-Antoni van Leeuwenhoek Hospital, Amsterdam, the Netherlands.
Small
March 2024
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, Shaanxi Normal University, Xi'an, 710062, P. R. China.
A sonication-assisted liquid-phase preparation technique is developed to prepare boron quantum dots (BQDs) with a lateral size of 3 nm in a solution of NMP and NBA; it shows a direct bandgap semiconductor with a bandgap of 3 eV and a specific capacitance of 41 F g . A BQDs(10)-Ti C T membrane electrode with excellent capacitance and high flexibility is prepared by using Ti C T nanosheets (NSs) as assembled units and BQDs as pillar; it gives a specific capacitance of 524 F g at 1 A g in 6 m H SO electrolyte, a high capacity retention of 75%, and a minimum relaxation time of 0.51 s.
View Article and Find Full Text PDFRes Child Adolesc Psychopathol
April 2023
Telethon Kids Institute, The University of Western Australia, Perth, WA, 6009, Australia.
Natural Language Sampling (NLS) offers clear potential for communication and language assessment, where other data might be difficult to interpret. We leveraged existing primary data for 18-month-olds showing early signs of autism, to examine the reliability and concurrent construct validity of NLS-derived measures coded from video-of child language, parent linguistic input, and dyadic balance of communicative interaction-against standardised assessment scores. Using Systematic Analysis of Language Transcripts (SALT) software and coding conventions, masked coders achieved good-to-excellent inter-rater agreement across all measures.
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