An Interfacial Electron Transfer on Tetrahedral NiS /NiSe Heterocages with Dual-Phase Synergy for Efficiently Triggering the Oxygen Evolution Reaction.

Tetrahedral NiS /NiSe heterocages with rich-phase boundaries are synthesized through a simultaneous sulfuration/selenylation process using Ni-based acetate hydroxide prisms as precursor. Such a nanocage-like NiS /NiSe heterostructure can expose more active sites, accelerate the mass transport of the ions/gas, and optimize the interfacial electronic structure, which shows a significantly lower overpotential of 290 mV at 20 mA cm than those of NiS/NiS and NiSe as counterparts. The experimental characterizations and theoretical density functional theory (DFT) calculations unveil that the interfacial electron transfer from NiSe to NiS at the heterointerface can modulate the electronic structure of NiS /NiSe , which further cooperates synergistically to change the Gibbs free energy of oxygen-containing intermediates as the rate-determining step (RDS) from 2.16 eV (NiSe ) and 2.10 eV (NiS ) to 1.86 eV (NiS /NiSe heterostructures) during the oxygen evolution reaction (OER) process. And as a result, tetrahedral NiS /NiSe heterocages with dual-phase synergy efficiently trigger the OER process, and accelerate the OER kinetics. This work provides insights into the roles of the interfacial electron transfer in electrocatalysis, and can be an admirable strategy to modulate the electronic structure for developing highly active electrocatalysts.