Zinc-catalyzed synthesis of acylsilanes using carboxylic acids and a silylborane has been achieved in the presence of pivalic anhydride. Various carboxylic acids were converted to the corresponding acylsilanes. The in situ formation of mixed anhydrides was essential in the present reaction.
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| http://dx.doi.org/10.1021/acs.orglett.9b04151 | DOI Listing |
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