We present a multi-instrument experiment to study the effects of tropospheric thunderstorms on the mesopause region and the lower ionosphere. Sodium (Na) lidar and ionospheric observations by two digital ionospheric sounders are used to study the variation in the neutral metal atoms and metallic ions above thunderstorms. An enhanced ionospheric sporadic E layer with a downward tidal phase is observed followed by a subsequent intensification of neutral Na number density with an increase of 600 cm in the mesosphere. In addition, the Na neutral chemistry and ion-molecule chemistry are considered in a Na chemistry model to simulate the dynamical and chemical coupling processes in the mesosphere and ionosphere above thunderstorms. The enhanced Na layer in the simulation obtained by using the ionospheric observation as input is in agreement with the Na lidar observation. We find that the intensification of metallic layered phenomena above thunderstorms is associated with the atmospheric tides, as a result of the troposphere-mesosphere-ionosphere coupling.
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http://dx.doi.org/10.1038/s41598-019-54450-1 | DOI Listing |
Langmuir
March 2025
China Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China.
In the context of scarce metal resources, the one-step separation and recovery of high-value copper metal ions from secondary resources is of significant importance and presents substantial challenges. This study identified a Zn-based triazole MOF (Zn(tr)(OAc)) with accessible and noncoordinated terminal hydroxyl groups within its framework. The Zn(tr)(OAc) surpasses most currently reported Cu-specific MOF adsorbents regarding adsorption capacity and Cu selectivity.
View Article and Find Full Text PDFJ Environ Sci (China)
August 2025
Hubei Key Laboratory for Heavy Rain Monitoring and Warning Research, Institute of Heavy Rain, CMA, Wuhan 430205, China.
Under the current global climate change background, the response of soil heavy metals in the Qinghai Tibet Plateau basin to the intensification of climate change is still unclear, leading to the intensification of heavy metal migration in the watershed. We selected cadmium (Cd) in soils of the Taohe River Basin on the Tibetan Plateau as the study object, and established a heavy metal migration simulation model based on the Soil and Water Assessment Tool (SWAT) to estimate the impact of climate change on Cd migration in the basin. The results indicated that the drought indexes and precipitation were the main determinants of the changes in Cd migration in the basin.
View Article and Find Full Text PDFSci Total Environ
March 2025
Molecular Genetics Laboratory, Department of Botany, University of North Bengal, Siliguri 734013, India. Electronic address:
Heavy metals and metalloids (HMMs) pollution is an escalating global concern, driven by rapid industrialization, urbanization, and agricultural intensification. Contaminated soil not only compromise crop productivity but also introduce toxic elements into the food chain, posing serious risks to human health and ecological integrity. This study investigates the extent of HMMs-contamination (As, Cd, Pb, Ni, Cu, and Zn) in agricultural soils across the Gangetic plain and surrounding industrial regions of West Bengal, India, a microcosm of global challenges in soil pollution.
View Article and Find Full Text PDFSoft Matter
March 2025
Dept. of Chemical Engineering, Imperial College London, South Kensington, SW7-2AZ, London, UK.
This study explores the use of squid pen protein to enhance the chemical stability and heavy metal ion (Cu and Zn) affinity of β-chitosan. Hydrogel beads with enhanced porosity and scalability were prepared using 1-butyl-3-methylimidazolium acetate, ([BMIM][OAc]), which simultaneously functionalized β-chitosan by decreasing its crystallinity and enhancing binding site access, as indicated by Fourier transform infrared (FT-IR) spectroscopy, which revealed intensification of functional group expression. Notably, this functionalization compensated for the effects of glutaraldehyde crosslinking.
View Article and Find Full Text PDFColloids Surf B Biointerfaces
February 2025
Institute of Bioengineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China; ZJU-Hangzhou Global Scientific and Technological Innovation Centre, Hangzhou, Zhejiang 311200, China. Electronic address:
Lanthanide (Ln) elements form a cofactor complex with pyrroloquinoline quinone (PQQ) in bacterial alcohol dehydrogenases (Ln-ADH). The lanthanide elements did not support Ln-ADH activity equally, with only early lanthanides (La-Gd) promoting high enzyme activity. However, the early lanthanides did not promote the activity equally and the detailed mechanism of Ln-ADH exhibiting different activity in the presence of different light Lns remains obscure.
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