Solid-state gas sensors are a cost-effective and well-spread alternative to conventional gas sensing, employable in most environments, ranging from homes and offices to harsh industrial scenarios. The emergence of carbon nanotubes (CNTs) as sensing material in solid-state gas sensors paved the way to a new class of devices, which are semitransparent, flexible, and with a remarkably low environmental impact. These devices, however, lack selectivity to other gases and concurring physical phenomena, such as temperature and pressure changes. In this contribution, we show how by measuring the impedance of CNT-based gas sensors at different frequencies, it is possible to evaluate sensitivity coefficient for the immediate compensation of moisture content in the air, while still preserving in the considered ranges of average sensitivities as high as 0.045, 0.112, 7.842 × 10, and 0.041 % /ppm for ammonia, carbon dioxide, carbon monoxide and ethanol gas, respectively. With this simple approach, it will be possible to develop simple sensor read-out systems, with reduced external electronic, simplifying the route to low-cost and low-power sensor nodes for the internet of things.
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http://dx.doi.org/10.1021/acssensors.9b01095 | DOI Listing |
Photoacoustics
February 2025
College of Engineering, Department of Electrical and Electronic Engineering, Southern University of Science and Technology, Shenzhen 518055, China.
A novel balloon-type photoacoustic cell (BTPAC) is proposed to facilitate the detection limitations of acetylene (CH) gas achieving ppb level. Here, an ellipsoidal photoacoustic cavity is employed as the platform for gas-light interaction. By strategically directing the excitation source towards the focal point of the ellipsoidal cavity, ensuring its trajectory traverses the focal point upon each reflection from the interior walls.
View Article and Find Full Text PDFEnergy Fuels
January 2025
PolySense Lab, Dipartimento Interateneo di Fisica, University and Polytechnic of Bari, Via Amendola 173, Bari 70126, Italy.
A compact and portable gas sensor based on quartz-enhanced photoacoustic spectroscopy (QEPAS) for the detection of methane (C1), ethane (C2), and propane (C3) in natural gas (NG)-like mixtures is reported. An interband cascade laser (ICL) emitting at 3367 nm is employed to target absorption features of the three alkanes, and partial least-squares regression analysis is employed to filter out spectral interferences and matrix effects characterizing the examined gas mixtures. Spectra of methane, ethane, and propane mixtures diluted in nitrogen are employed to train and test the regression algorithm, achieving a prediction accuracy of ∼98%, ∼96%, and ∼93% on C1, C2, and C3, respectively.
View Article and Find Full Text PDFSci Rep
January 2025
Physics Department, Faculty of Science, Beni-Suef University, Beni-Suef, 62512, Egypt.
This paper presents a novel investigation of a magnetic sensor that employs Fano/Tamm resonance within the photonic band gap of a one-dimensional crystal structure. The design incorporates a thin layer of gold (Au) alongside a periodic arrangement of Tantalum pentoxide ([Formula: see text]) and Cesium iodide ([Formula: see text]) in the configuration [Formula: see text]. We utilized the transfer matrix method in conjunction with the Drude model to analyze the formation of Fano/Tamm states and the permittivity of the metallic layer, respectively.
View Article and Find Full Text PDFInorg Chem
January 2025
School of Materials Science and Engineering, Hainan University, Haikou 570228, China.
Hydrogen-bonded organic frameworks (HOFs) are under fast development in broad applications but have not been well explored for chemiresistive gas sensing yet primarily due to insufficient active sites. Herein, a new porphyrin-based HOF-199 is constructed by OH···O hydrogen bonds featuring layered networks and rich free oxygen (O) atoms, which is further exfoliated into few-layer nonosheets with more dangling O sites through an ultrasound-assisted liquid exfoliation method (namely L-HOF-199). Benefiting from rich electron-donor sites, L-HOF-199 demonstrates exceptional NO sensing properties under ambient conditions, achieving a remarkable 3.
View Article and Find Full Text PDFJ Mol Graph Model
January 2025
Department of Chemistry Education, Farhangian University, P.O. Box 14665-889, Tehran, Iran. Electronic address:
In this study, the need for efficient detection of volatile organic compounds (VOCs) in environmental monitoring, industrial safety, is addressed by investigating borophene-based B36 nanoclusters as gas sensors. Density functional theory (DFT) calculations were employed to examine the adsorption behavior of ethanol, isobutanol, and acetone on B surfaces, with a focus on vibrational modes, reactivity, and adsorption energies. It was found that acetone exhibits the strongest interaction with pristine B, indicating its potential for robust sensing applications.
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