An experimental study with respect to the effect of an alternating electropulsing on grain refinement in pure aluminum was reported. The macrostructural observation with the mold preheated to different temperature and embedded the metal mesh indicated that the change of electric current-associated free energy related with the position of crystal nuclei (Δ) and forced convection dominated the generation of fine equiaxed grains (FEG). Under electropulsing with 480 A, Δ induced the dissociation of crystal nuclei from the upper interface of the electrode and the melt, leading to the generation of FEG. For a larger current intensity, FEG originated from the dissociation of crystal nuclei on the side wall besides the upper interface due to Δ and the forced convection. Furthermore, the model coupling the dissociation of crystal nuclei and dendrite fragmentation due to the forced convection and the dissociation of crystal nuclei due to Δ was presented to explain the formation mechanism of FEG in pure aluminum under electropulsing.
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http://dx.doi.org/10.3390/ma12233846 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Department of Anatomy and Physiology, Kansas State University, Manhattan, Kansas 66506, United States.
Metal flux methods are excellent for synthesizing high-quality hexagonal boron nitride (hBN) crystals, but the atomic mechanisms of hBN nucleation and growth in these systems are poorly understood and difficult to probe experimentally. Here, we harness classical reactive molecular dynamics (ReaxFF) to unravel the mechanisms of hBN synthesis from liquid nickel solvent over time scales up to 30 ns. These simulations mimic experimental conditions by including relatively large liquid nickel slabs containing dissolved boron and a molecular nitrogen gas phase.
View Article and Find Full Text PDFAdv Mater
January 2025
Key Lab of Artificial Micro- and Nano-Structures of Ministry of Education of China, School of Physics and Technology, Wuhan University, Wuhan, 430072, China.
Porous lead iodide (PbI) film is crucial for the complete reaction between PbI and ammonium salts in sequential-deposition technology so as to achieve high crystallinity perovskite film. Herein, it is found that the tensile stress in tin (IV) oxide (SnO) electron transport layer (ETL) is a key factor influencing the morphology and crystallization of PbI films. Focusing on this, lithium trifluoromethanesulfonate (LiOTf) is used as an interfacial modifier in the SnO/PbI interface to decrease the tensile stress to reduce the necessary critical Gibbs free energy for PbI nuclei formation.
View Article and Find Full Text PDFACS Omega
January 2025
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 50/38 Akademgorodok, Krasnoyarsk 330036, Russia.
The magnetization and anisotropy of magnetic susceptibility of a 5CB nematic liquid crystal doped three extracts containing chlorophylls a and b and carotenoids in different weight percentage has been studied. The extracts have been dissolved in the liquid crystal matrix at a concentration of 2%. The magnetic susceptibility of the substances has been measured by the Faraday-Curie balance method.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China.
The nuclear membrane is a double-layered structure that physically protects the cell's DNA from the chemical reactions occurring in other parts of the cell. In this study, we present the first brand-new small-molecule fluorescent probe that selectively stains the nuclear membrane, allowing for the visualization of nuclear morphology without interfering with the DNA's activity.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Soft Condensed Matter & Biophysics, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 1, 3584 CC Utrecht, The Netherlands.
Since the influential work of ten Wolde, Ruiz-Montero, and Frenkel [Phys. Rev. Lett.
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