A phthaloyl-protected aminooxymethyl--2'-deoxyriboside building block has been prepared and incorporated in the middle of an oligodeoxyribonucleotide. Removal of the phthaloyl protection followed by on-support oximation with either mercurated or palladated benzaldehydes yielded oligonucleotides bearing the respective benzaldoxime metallacycles.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6854833 | PMC |
http://dx.doi.org/10.1021/acsomega.9b02804 | DOI Listing |
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