In this study, the effects of spinodal decomposition on the microstructures and mechanical properties of a TiZrNbTa alloy are investigated. The as-cast TiZrNbTa alloy possesses dual phases of TiZr-rich inter-dendrite (ID) and NbTa-rich dendrite (DR) domains, both of which have a body-centered cubic (BCC) structure. In the DRs of the as-cast alloy, the α and ω precipitates are found to be uniformly distributed. After homogenization at 1100 °C for 24 h followed by water quenching, spinodal decomposition occurs and an interconnected structure with a wavelength of 20 nm is formed. The α and ω precipitates remained in the structure. Such a fine spinodal structure strengthens the alloy effectively. Detailed strengthening calculations were conducted in order to estimate the strengthening contributions from the α and ω precipitates, as well as the spinodal decomposition microstructure.
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http://dx.doi.org/10.3390/ma12213508 | DOI Listing |
Nanomaterials (Basel)
January 2025
Key Laboratory of Optoelectronic Materials and Devices, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China.
Antimonide laser diodes, with their high performance above room temperature, exhibit significant potential for widespread applications in the mid-infrared spectral region. However, the laser's performance significantly degrades as the emission wavelength increases, primarily due to severe quantum-well hole leakage and significant non-radiative recombination. In this paper, we put up an active region with a high valence band offset and excellent crystalline quality with high luminescence to improve the laser's performance.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Physics, National University of Singapore, Singapore 117551, Singapore.
Phase separation plays a crucial role in many natural and industrial processes, such as the formation of clouds and minerals and the distillation of crude oil. In metals and alloys, phase separation is an important approach often utilized to improve their mechanical strength for use in construction, automobile, and aerospace manufacturing. Despite its importance in many processes, the atomic details of phase separation are largely unknown.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
National Center for Materials Service Safety, University of Science and Technology Beijing, 30 Xueyuan Road, Beijing 100083, China.
Microstructure and deformation properties of both unaged and aged cladding material were studied at 400 °C for 10,000 h. The results indicated that carbide formation occurred in the cladding material, while thermal aging treatment resulted in spinodal decomposition and G-phase formation in the aged ferrite phase. Furthermore, intensive straight slip bands formed in both unaged and aged austenite phases.
View Article and Find Full Text PDFNano Lett
January 2025
Department of Chemical Engineering and Materials Science, University of Minnesota-Twin Cities, Minneapolis, Minnesota 55455, United States.
Rutile GeO and related materials are attracting interest due to their ultrawide band gaps and potential for ambipolar doping in high-power electronic applications. This study examines the growth of rutile SnGeO films through oxygen-plasma-assisted hybrid molecular beam epitaxy (hMBE). The film composition and thickness are evaluated across a range of growth conditions, with the outcomes rationalized by using density functional theory calculations.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
CAS Key Laboratory of Magnetic Materials and Devices, and Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China.
The glacial phase can be formed from supercooled liquid (SCL) in certain systems, which is called liquid-liquid transition (LLT). Revealing the nature of the glacial phase especially in a single-component system is crucial for understanding the LLT process. Here, by using flash differential scanning calorimetry and cold-field transmission electron microscopy, the structure of the d-mannitol glacial phase and the phase transition kinetics between the glacial phase and SCL were studied.
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