We present a high-throughput (combinatorial) method to screen thin ceramic films as Li-ion conductors by mapping an optical effect of Li-ion conduction. The method, while qualitative, is fast and simple to implement, provides a planar (XY) map of Li-ion conductivity through different parts of the film. The effect, , is an optoelectrochemical one that relies on darkening of the FTO (F-doped tin oxide) substrate, onto which the investigated film is deposited. The rate of color change of the FTO reflects the rate of Li-ion migration through the film. The method is validated by testing two model systems, a Li-La-S-O film with uniform composition and varying thickness, and a Li-La-P-O film with varying thickness and lateral composition. The darkening rate, obtained from optical transmission, correlates linearly with inverse film thickness. The darkening rate map can be compared with a resistance map obtained by impedance measurements, showing that only Li conduction is measured. We discuss the conditions required to distinguish between areas with pure ion conductivity and those with mixed conductivity, the reversibility of the darkening effect and artifacts.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acscombsci.9b00099 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Effect of Balangu seed mucilage/gelatin coating containing dill essential oil and ZnO nanoparticles on sweet cherry quality during cold storage.
Heliyon
December 2024
Department of Food Science and Engineering, Faculty of Agriculture, University of Zanjan, Zanjan, 45371-38791, Iran.
The current research focused on examining the effect of a coating made from Balangu seed mucilage (TSM-BM) and gelatin (Ge), with varying concentrations of dill essential oil (DEO) (0 %, 1 %, and 2 %) and zinc oxide nanoparticles (ZnO-np) (0 % and 0.5 %), on the quality characteristics of cherries stored at 4 °C over intervals of 0, 4, 7, 11, 18, and 25 days. The study noted that the application of this coating, particularly when combined with DEO and ZnO-np, significantly reduced the rate of changes in several parameters, including weight loss, firmness, titratable acidity, pH, total soluble solids, ascorbic acid, total anthocyanin content, total phenolic content, and antioxidant activity (p˂0.
View Article and Find Full Text PDFTriple Therapy with Budesonide/Glycopyrronium/Formoterol Fumarate Dihydrate versus Dual Therapies for Patients with COPD and Phenotypic Features of Asthma: A Pooled Post Hoc Analysis of KRONOS and ETHOS.
Int J Chron Obstruct Pulmon Dis
December 2024
AstraZeneca, Cambridge, UK.
Background: We evaluated the inhaled corticosteroid/long-acting muscarinic antagonist/long-acting β-agonist (ICS/LAMA/LABA) triple therapy with budesonide/glycopyrronium/formoterol fumarate dihydrate (BGF) versus dual LAMA/LABA and ICS/LABA therapies in patients with chronic obstructive pulmonary disease (COPD) and phenotypic features of asthma (bronchodilator reversibility and elevated blood eosinophils), but no asthma diagnosis, for whom treatment guidelines are limited.
Patients And Methods: KRONOS (NCT02497001) and ETHOS (NCT02465567) enrolled patients with moderate-to-very-severe COPD, no current asthma diagnosis, and either ≥0 (KRONOS) or ≥1 (ETHOS) moderate/severe exacerbations in the prior year. This pooled post hoc analysis evaluated trough forced expiratory volume in 1 second (FEV) and FEV area under the curve from hours 0 to 4 (AUC) change from baseline over 12-24 weeks, moderate/severe exacerbation rates, and St George's Respiratory Questionnaire (SGRQ) total score over 24 weeks with ICS/LAMA/LABA (BGF 320/14.
Methyl jasmonate enabled maintained the postharvest flavor quality of ginger (Zingiber officinale roscoe) by reducing the loss of terpene volatile compounds.
Food Chem
December 2024
Hubei key Laboratory of Spices & Horticultural Plant Germplasm Innovation & Utilization, College of Horticulture and Gardening, Yangtze University, Jingzhou 434025, Hubei, China; Spice Crops Research Institute, College of Horticulture and Gardening, Yangtze University, Jingzhou 434025, Hubei, China; College of Smart Agriculture /Institute of Special Plants, Chongqing University of Arts and Sciences, Yongchuan 402160, Chongqing, China. Electronic address:
Ginger, as a globally vital medicinal and food homologous crop, plays an irreplaceable role in human diet and healthcare. However, during the storage of ginger, the decline of physical properties and degradation of volatile flavor quality have emerged as an industrial concern that severely restricts the market value of the product. MeJA plays an essential role in extending fruit shelf life and regulate the synthesis of volatiles in horticultural products, yet its application in ginger remains unreported.
View Article and Find Full Text PDFWhat causes the urban river to look darker? An underestimated source of sulfide production in methanogenic metabolism.
J Hazard Mater
December 2024
Institute of Environmental Research at Greater Bay Area, Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Guangzhou University, Guangzhou 510006, China.
The blackening and increased smelling of waterbodies steadily affect urban aquatic ecology. Sulfide is recognized as the key substance responsible for the darkening of urban rivers. However, the pathway of sulfide production and the underling microbial mechanisms in urban rivers are not fully understood.
View Article and Find Full Text PDFSeparate sites of action for cry1 and phot1 blue-light receptors in the Arabidopsis hypocotyl.
Curr Biol
January 2025
Department of Botany, University of Wisconsin-Madison, 430 Lincoln Dr., Madison, WI 53706, USA. Electronic address:
Rapid cell expansion pushes the Arabidopsis hypocotyl (juvenile stem) through the soil until blue light, acting first through phototropin 1 (phot1) and then through cryptochrome 1 (cry1), suppresses elongation to produce a length characteristic of established, photosynthetically capable seedlings. To determine where these two different blue-light receptors act to suppress hypocotyl elongation, we measured relative elemental growth rate, specifically along the hypocotyl midline at 5-min intervals before and during blue light, using a machine-learning-based image analysis pipeline designed specifically for this kinematic analysis of growth. In darkness, hypocotyl material expanded most rapidly (approximately 4% h) in a broad zone approximately 1 mm below the apical terminus of the hypocotyl (cotyledonary node).
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!