Supramolecular self-assembly behaviors on solid substrates have been widely investigated in the last few decades. Owing to the complexity of interfacial assembly systems, the precise regulation of supramolecular nanostructures is still challenging and waits to be solved. The supramolecular nanostructures are governed by non-covalent bonds, so they can be disrupted and influenced by an external environment. In this review, the dynamic supramolecular nanostructures that are mediated by external stimuli containing guest species, light irradiation, temperature and electric field are discussed in detail. The research studies mentioned in this article are all accomplished by STM, and the effects of these external stimuli on the assembled nanostructures have been elucidated exhaustively here.
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