A modification of Slusher-Hahn's double resonance technique is described and experimentally tested. It is based on application of multiple frequency sweeps and can be used for a rapid location of nuclear quadrupole resonance (NQR) frequencies. The resolution of the present technique is relatively low but, when the NQR frequencies are located, it is easy to use either the Slusher-Hahn's technique or pulse NQR to determine the NQR frequencies with a higher precision.
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http://dx.doi.org/10.1016/j.jmr.2019.106635 | DOI Listing |
J Am Chem Soc
January 2025
Univ Rennes, ENSCR, CNRS, ISCR-UMR6226, Université de Rennes, Rennes 35042, France.
Metal halide perovskites, including some of their related perovskitoid structures, form a semiconductor class of their own, which is arousing ever-growing interest from the scientific community. With halides being involved in the various structural arrangements, namely, pure corner-sharing MX (M is metal and X is halide) octahedra, for perovskite networks, or alternatively a combination of corner-, edge-, and/or face-sharing for related perovskitoids, they represent the ideal probe for characterizing the way octahedra are linked together. Well known for their inherently large quadrupolar constants, which is detrimental to the resolution of nuclear magnetic resonance spectroscopy, most abundant halide isotopes (Cl, Br, I) are in turn attractive for magnetic field-free nuclear quadrupolar resonance (NQR) spectroscopy.
View Article and Find Full Text PDFSolid State Nucl Magn Reson
December 2023
Godo Shigen Co. Ltd. , Chiba Iodine Resource Innovation Center, Chiba University, 1-33 Yayoi-Cho, Inage-Ku, Chiba, 263-8522, Japan.
Field-stepwise-swept solid-state I NMR experiments of 1,4-diiodobenzene, CHI, applied to a Zeeman-perturbed NQR region, have been presented. A series of QCPMG measurements is performed at T = 90 K with resonant frequencies of 271 MHz in the range of magnetic fields from 2.5 T to zero with the interval of 12 mT.
View Article and Find Full Text PDFJ Magn Reson
December 2023
Faculty of Science, Course for Physical Sciences, Kumamoto University, Kurokami, Kumamoto 860-8555, Japan.
We propose a data-driven technique to infer microscopic physical quantities from nuclear magnetic resonance (NMR) spectra, in which the data size and quality required for the Bayesian inference are investigated. The Co-NMR measurement of YbCoZn single crystal generates complex spectra with 28 peaks. By exploiting the site symmetry in the crystal structure, the isotropic Knight shift K and nuclear quadrupole resonance (NQR) frequency ν were respectively estimated to be K=0.
View Article and Find Full Text PDFJ Phys Chem A
October 2023
Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99354, United States.
We report a study of the temperature dependence of Cl nuclear quadrupole resonance (NQR) transition energies and spin-lattice relaxation times () for U-depleted dicesium uranyl tetrachloride (CsUOCl) aimed at elucidating electronic interactions between the uranium center and atoms in the equatorial plane of the UO ion. The transition frequency decreases slowly with temperature below 75 K and with a more rapid linear dependence above this temperature. The spin-lattice relaxation time becomes shorter with temperature, and as temperatures increase, the decrease becomes nearly quadratic.
View Article and Find Full Text PDFSci Adv
June 2023
Center for High Technology Materials and Department of Physics and Astronomy, University of New Mexico, Albuquerque, NM, USA.
Radio frequency (RF) magnetometers based on nitrogen vacancy centers in diamond are predicted to offer femtotesla sensitivity, but previous experiments were limited to the picotesla level. We demonstrate a femtotesla RF magnetometer using a diamond membrane inserted between ferrite flux concentrators. The device provides ~300-fold amplitude enhancement for RF magnetic fields from 70 kHz to 3.
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