Intensified interzeolite transformation: ultrafast synthesis of active and stable Ti-Beta zeolites without solvents.

Chem Commun (Camb)

Shanghai Key Laboratory of Green Chemistry and Chemical Process, School of Chemistry and Molecular Engineering, East China Normal University, North Zhongshan Rd. 3663, Shanghai 200062, China.

Published: November 2019

This study proposes a novel strategy for preparing Ti-Beta zeolite with nanosized crystals and incredibly stable isolated Ti4+ ions under solvent-free conditions via intensified interzeolite transformation from a commercially available Ti-MWW source. The obtained Ti-Beta exhibited unique catalytic performance in the oxidation of cyclohexene with aqueous hydrogen peroxide.

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Source
http://dx.doi.org/10.1039/c9cc07423fDOI Listing

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