We report the first proof of concept for a nonaqueous, all-organic semisolid flow battery (SSFB) using suspensions of 10-methylphenothiazine@Ketjen black and thioxanthone@Ketjen black dispersed in tetraethylammonium hexafluorophosphate/acetonitrile as the cathode and anode, respectively. A proof of principle cell with an open circuit voltage of 2.35 V demonstrated an average coulombic efficiency of 83% within the voltage range 3.0-0 V. This study provides a potential path for developing new high energy density and cost-effective nonaqueous organic SSFBs.
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http://dx.doi.org/10.1039/c9cc07937h | DOI Listing |
Nanomaterials (Basel)
December 2024
Material Science, BASF SE, RGA/BM-B007, Carl-Bosch-Str. 38, D-67056 Ludwigshafen, Germany.
The controlled formation and stabilization of nanoparticles is of fundamental relevance for materials science and key to many modern technologies. Common synthetic strategies to arrest growth at small sizes and prevent undesired particle agglomeration often rely on the use of organic additives and require non-aqueous media and/or high temperatures, all of which appear critical with respect to production costs, safety, and sustainability. In the present work, we demonstrate a simple one-pot process in water under ambient conditions that can produce particles of various transition metal carbonates and sulfides with sizes of only a few nanometers embedded in a silica shell, similar to particles derived from more elaborate synthesis routes, like the sol-gel process.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
December 2024
Institute of Forestry and Engineering, Estonian University of Life Sciences, 51014, Tartu, Estonia.
In this work, a comparison of the photocatalytic activity of free-standing Cu-based nanoparticle mixtures and spin-coated nanoparticle films under visible-light radiation is conducted. Herein, CuO, CuO-Cu, CuO-CuN-Cu, and CuN-Cu nanoparticle mixtures were successfully synthesized by a non-aqueous sol-gel route and then deposited on a glass substrate by spin-coating. The surface chemistry of the nanoparticles studied by X-ray photoelectron spectroscopy (XPS) allowed elucidating the nanoparticle synthesis mechanism.
View Article and Find Full Text PDFSmall
December 2024
Department of Chemical Engineering, University of Illinois Chicago, Chicago, IL, 60607, USA.
Electrochemical CO reduction reaction (CO-RR) in non-aqueous electrolytes offers significant advantages over aqueous systems, as it boosts CO solubility and limits the formation of HCO and CO anions. Metal-organic frameworks (MOFs) in non-aqueous CO-RR makes an attractive system for CO capture and conversion. However, the predominantly organic composition of MOFs limits their electrical conductivity and stability in electrocatalysis, where they suffer from electrolytic decomposition.
View Article and Find Full Text PDFDalton Trans
December 2024
Department of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, KS 66045, USA.
Polym Chem
December 2024
Polymer Science, Zernike Institute for Advanced Materials, University of Groningen Nijenborgh 4 9747 AG Groningen The Netherlands
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