Dynamical Origin of the Total and Zero-Point Kinetic Energy in a Quantum Fluid.

Phys Rev Lett

Consiglio Nazionale delle Ricerche, Istituto di Fisica Applicata "Nello Carrara," via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy.

Published: September 2019

By applying an exponential mode analysis to ring polymer molecular dynamics simulations of dense fluid parahydrogen, we find that the dynamical processes establishing the time behavior of the Kubo velocity autocorrelation function display the same nature as those already observed in high-density classical fluids. This result permits us to demonstrate that the exponential mode decomposition is a unique tool to identify which dynamical processes lead to one of the most notable properties of quantum fluids: the large value of the mean kinetic energy per particle and the importance of the zero-temperature quantum effects in determining it.

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http://dx.doi.org/10.1103/PhysRevLett.123.135301DOI Listing

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