Invited for the cover of this issue are the groups of Janusz Lewiński from Polish Academy of Sciences and Warsaw University of Technology. The image depicts how a zinc ethylsulfinate web can be woven by using diethylzinc and sulfur dioxide. Read the full text of the article at 10.1002/chem.201902733.
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http://dx.doi.org/10.1002/chem.201904162 | DOI Listing |
Chemistry
November 2019
Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland.
Chemistry
November 2019
Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland.
The ability to utilize polluting gases in efficient metal-mediated transformations is one of the most pressing challenges of modern chemistry. Despite numerous studies on the insertion of SO into M-C bonds, the chemical reaction of SO with organozinc compounds remains little explored. To fill this gap, we report here the systematic study of the reaction of Et Zn towards SO as well as the influence of Lewis bases on the reaction course.
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