The structural, magnetic and Mössbauer spectral properties of a double salt, mixed-valent material, [Fe(3,5-MeTPM)(TPM)][Fe(azp)]ClO·2MeCN, 1, reveal spin transitions occur at both the metal sites, with hysteresis, indicative of 1 being a double spin crossover material.
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http://dx.doi.org/10.1039/c9cc07416c | DOI Listing |
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