AI Article Synopsis
- The text discusses the discovery and detailed analysis of new compounds known as tetrakis(trimethylsilylsulfido) and -(trimethylsilylselenido) gallates and indates, presented as their organic salt forms.
- These compounds can serve as versatile precursors for the low-temperature creation of complex metal chalcogenide materials, like the CIGS species (Copper Indium Gallium Selenide/Sulfide).
- The research highlights their potential applications in developing new materials for various technological purposes.
Article Abstract
We communicate the synthesis and full characterization of so far unknown tetrakis(trimethylsilylsulfido) and -(trimethylsilylselenido) gallates and indates in form of their organic salts Cat[M(ESiMe)] (M = Ga, In; E = S, Se; Cat = dimethylpyrrolidinium (DMPyr), PhP, (dppe)Cu, (dmpe)Cu). These thermally metastable silylchalcogenolatometalates can act as modular precursors for an ionic-liquid- or organic-solution-based low-temperature synthesis of multinary metal chalcogenide materials such as the CIGS species Cu(InGa)(SSe).
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| http://dx.doi.org/10.1021/acs.inorgchem.9b02453 | DOI Listing |
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