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From a layered iridium(iii)-cobalt(ii) organophosphonate to an efficient oxygen-evolution-reaction electrocatalyst. | LitMetric

From a layered iridium(iii)-cobalt(ii) organophosphonate to an efficient oxygen-evolution-reaction electrocatalyst.

Chem Commun (Camb)

State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, P. R. China.

Published: November 2019

AI Article Synopsis

  • * The study focuses on a layered bimetallic-organophosphonate composed of Iridium (Ir), Cobalt (Co), and Phosphorus (P), leveraging their efficiency in the oxygen-evolution reaction (OER) with phosphate serving as a proton carrier.
  • * The calcined MOF exhibited impressive OER performance in 1.0 M KOH, with an overpotential of 317.7 mV at 10 mA cm-2 and a low Tafel slope of 59.1 mV dec-1.

Article Abstract

Bimetallic MOF precursors can produce a homogeneous distribution of mixed-metal oxides after calcination, and thus may provide high efficiency as electrocatalysts in the water splitting process. We designed a layered bimetallic-organophosphonate containing Ir, Co and P because the metal-oxides are well-known for their efficiency in the oxygen-evolution reaction (OER), especially when the phosphate acts as a proton carrier. We describe the structure of the MOF and characteristics of the calcined form, which has outstanding OER characteristics in 1.0 M KOH with an overpotential of 317.7 mV at 10 mA cm-2 and a low Tafel slope of 59.1 mV dec-1.

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Source
http://dx.doi.org/10.1039/c9cc06164aDOI Listing

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