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Decarboxylative C-N Bond Formation by Electrochemical Oxidation of Amino Acids. | LitMetric

Decarboxylative C-N Bond Formation by Electrochemical Oxidation of Amino Acids.

Org Lett

Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering , Nanjing Tech University, Nanjing 211816 , China.

Published: November 2019

Decarboxylative C-N coupling reactions have been developed through electrochemical oxidation of amino acids. The reaction proceeds via anodic oxidative decarboxylation of carboxylic acids to form stabilized carbocations, which are trapped by azoles or amides to construct C-N bonds. This method avoids the preactivation of carboxylic acids and the use of expensive transition-metals and external chemical oxidants.

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Source
http://dx.doi.org/10.1021/acs.orglett.9b03696DOI Listing

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