Preparation of Pd/C by Atmospheric-Pressure Ethanol Cold Plasma and Its Preparation Mechanism.

Treatment with atmospheric-pressure (AP) hydrogen cold plasma is an effective method for preparing highly active supported metal catalytic materials. However, this technique typically uses H as working gas, which is explosive and difficult to transport. This study proposes the use of PdCl as a Pd precursor and activated carbon as the support to fabricate Pd/C catalytic materials (Pd/C-EP-Ar) by using ethanol-which is renewable, easily stored, and safe-combined with AP cold plasma (AP ethanol cold plasma) followed by calcination in Ar gas at 550 °C for 2 h. Both Pd/C-EP and Pd/C-HP fabricated using AP ethanol and hydrogen cold plasma (without calcination in Ar gas) respectively, exhibit low CO oxidation reactivity. The activity of Pd/C-EP is lower than Pd/C-HP, which is mainly ascribed to the carbon layer formed by ethanol decomposition during plasma treatment. However, the 100% CO conversion temperature () of Pd/C-EP-Ar is 140 °C, which is similar to that of Pd/C-HP-Ar fabricated using AP hydrogen cold plasma (calcined in Ar gas at 550 °C for 2 h). The characterization results of X-ray diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy indicated that the carbon layer formed by ethanol decomposition enhanced the interaction of metal nanoparticles to the support, and a high Pd/C atomic ratio was obtained. This was beneficial to the high CO oxidation performance. This work provides a safe method for synthesizing high-performance Pd/C catalytic materials avoiding the use of H, which is explosive and difficult to transport.