Epoxy polymer concrete (EPC) has found increasing applications in infrastructure as a rising candidate among civil engineering materials. In most of its service environments, EPC is inevitably exposed to severe weather conditions, e.g., violent changes in temperature, rain, and ultraviolet (UV) radiation. In this paper, we designed an accelerated aging test for EPC, which includes periodic variation of temperature and water spray, as well as intensive UV-light irradiation, imitating the outdoor environment in South China. The experimental results show that the flexural performance of EPC is found deteriorate with the aging time. An aging process equivalent to four years (UV radiation dose) results in up to 8.4% reduction of flexural strength. To explore the mechanisms of observed performance degradation, the EPC specimen in the four-point-bending test is considered as a layered beam. The analysis indicates that the loss of flexural load-carrying capacity of an aged EPC beam is dominated by the reduction of mechanical properties of the surface layer. The mechanical properties of the surface layer are closely associated with the aging of epoxy mortar, which can be approximated as a reciprocal function of the aging time. By introducing damage to the surface layer into the layered beam, the proposed model demonstrates a good ability to predict the residual flexural strength of EPC during the aging process.
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http://dx.doi.org/10.3390/ma12213472 | DOI Listing |
Environ Sci Pollut Res Int
January 2025
Department of Agricultural Chemistry, National Taiwan University, Taipei, 106319, Taiwan.
Rare earth elements (REEs) are emerging contaminants rendering potential risks in soils to environmental quality and human health. The causation between their geochemical signatures and contamination levels with parent rocks and soil properties are critical for REEs risk assessments, which are urgently needed globally. Thus, this study aimed to elucidate cause-and-effect among hydrofluoric-acid-digested total and ethylenediaminetetraacetic acid extracted bioavailable soil REEs and their contamination degree evaluated by pollution indices in 268 soil layer (horizon) samples from 50 soil profiles derived from felsic, intermediate, mafic, ultramafic, and sedimentary rocks in Taiwan.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
School of Engineering and Materials Science, Queen Mary University of London, Mile End Road, London E1 4NS, United Kingdom. Electronic address:
Understanding the architecture and mechanism of assembly of polyelectrolyte-nucleic acid complexes is critical to the rational design of their performance for gene delivery. Surface-initiated polymer brushes were recently found to be particularly effective at delivering oligonucleotides and maintaining high knock down efficiencies for prolonged periods of time, in highly proliferative cells. However, what distinguishes their binding capacity for oligonucleotides from that of larger therapeutic macromolecules remains unknown.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou, Jiangsu Province 213164, China. Electronic address:
Despite the advancement of the Pt-catalyzed hydrogen evolution reaction (HER) through oxophilic metal-hydroxide surface hybridization, its stability in acidic solutions remains unsatisfactory. This is primarily due to excessive aggregation of active hydrogen, which hinders subsequent hydrogen desorption, coupled with the poor operational stability of metal hydroxides. In this study, we have designed Pt nanoparticles-modified NiFeCoCuCr high-entropy layered double hydroxides (Pt/HE-LDH) that exhibit exceptional catalytic activity toward HER in acidic electrolytes.
View Article and Find Full Text PDFAtherosclerosis
January 2025
State Key Laboratory of Frigid Zone Cardiovascular Diseases (SKLFZCD), Key Laboratory of Myocardial Ischemia, Chinese Ministry of Education, Department of Cardiology of the Second Affiliated Hospital, Harbin Medical University, Harbin, Heilongjiang, China. Electronic address:
Background And Aims: Histologic studies indicated that healed plaque, characterized by a multilayered pattern, is indicative of prior atherothrombosis and subsequent healing. However, longitudinal in vivo data on healed plaque formation in non-culprit plaques are limited. This study aimed to investigate serial changes and clinical significance of new layered pattern formation in non-culprit plaques in patients with acute coronary syndromes (ACS) using serial optical coherence tomography (OCT) imaging.
View Article and Find Full Text PDFMar Pollut Bull
January 2025
CSIR-National Institute of Oceanography, Dona Paula, Goa 403004, India.
Coastal deoxygenation impacts phytoplankton communities crucial for marine productivity. The inter- and intra-annual variability in phytoplankton communities at a shallow (27 m) station over the Western Indian Shelf (CaTS site, off Goa) during deoxygenation events of the late southwest monsoon (LSWM September-October) were studied from 2020 to 2023. The water column (0-27 m depth) experienced seasonal hypoxia/anoxia at subsurface depths (0-1.
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