Copper-Catalyzed Diphenylation of P(O)-OH Bonds with Cyclic Diaryliodonium Salts.

Chem Asian J

Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom, Hong Kong, P. R. China.

Published: December 2019

A copper-catalyzed diphenylation of P(O)-OH bonds with cyclic diaryliodonium salts is described. Valuable 2'-iodo substituted biaryl phosphinic/phosphoric acid esters were obtained in good to excellent yields, which could be further transformed to diversified building blocks for the synthesis of bioactive compounds, pharmaceuticals and functional materials.

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http://dx.doi.org/10.1002/asia.201901284DOI Listing

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