AI Article Synopsis
- The compound [Cd(NO)(CHN)] features a cadmium (Cd) atom coordinated with four nitrogen (N) and two oxygen (O) atoms, resulting in a distorted octahedral structure.
- The geometry involves two bidentate 2-(1-benzimidazol-2-yl)aniline ligands, with a dihedral angle of 30.43° between the aniline and benzimidazole rings.
- Stability in the complex is provided by intra- and inter-molecular hydrogen bonds, contributing to a three-dimensional network in the crystal structure.
Article Abstract
In the title compound, [Cd(NO)(CHN)], the Cd atom lies on a twofold rotation axis and is coordinated by four N atoms and two O atoms, provided by two bidentate 2-(1-benzimidazol-2-yl)aniline ligands, and two nitrato O atoms, forming a distorted octa-hedral geometry [range of bond angles around the Cd atom = 73.82 (2)-106.95 (8)°]. In the ligand, the dihedral angle between the aniline ring and the benzimidazole ring system is 30.43 (7)°. The discrete complex mol-ecule is stabilized by an intra-molecular N-H⋯O hydrogen bond. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules, forming a three-dimensional network.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775742 | PMC |
| http://dx.doi.org/10.1107/S2056989019012416 | DOI Listing |
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