To date, reports on metal oxide semiconductors for selective detection of dimethylamine (DMA) is in scarce. Hence in our study, we report titanium oxide (TiO₂) as a promising candidate for tuned selectivity towards DMA. Highly uniform TiO₂ thin films were successfully deposited on glass substrates using reactive dc magnetron sputtering at various substrate temperatures. Polycrystalline nature of rutile TiO₂ was confirmed by X-ray diffraction technique (XRD). The uniform surface morphology of the sputtered TiO₂ thin films was revealed by Field Emission Scanning Electron Microscopy (FESEM). An upsurge in optical band gap from 3.18 to 3.4 eV was observed with increase in substrate temperature. The sensing studies of the sputtered TiO₂ thin films exhibited a significant sensor response towards the lower concentration of DMA at ambient temperature. It is deemed that this work will provide an insight to develop DMA sensors based on TiO₂ thin films.
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http://dx.doi.org/10.1166/jnn.2020.17199 | DOI Listing |
Nanomicro Lett
January 2025
Energy and Environmental Division, Korea Institute of Ceramic Engineering and Technology, Jinju, Gyeongnam, 52851, Republic of Korea.
All-solid-state batteries (ASSBs) are pursued due to their potential for better safety and high energy density. However, the energy density of the cathode for ASSBs does not seem to be satisfactory due to the low utilization of active materials (AMs) at high loading. With small amount of solid electrolyte (SE) powder in the cathode, poor electrochemical performance is often observed due to contact loss and non-homogeneous distribution of AMs and SEs, leading to high tortuosity and limitation of lithium and electron transport pathways.
View Article and Find Full Text PDFJ Opt Soc Am A Opt Image Sci Vis
August 2024
In this paper, a new theoretical model of a partially coherent Laguerre-Gaussian (LG) beam carrying multiple off-axis vortex phases was established. The evolution properties of the focused intensity of the beam after passing through a thin lens were theoretically studied, and then the modulation effect of multiple off-axis vortex phases on the beam with multiring structured intensity was explored. The results indicate that the multiple off-axis vortex phases can reconstruct the multiring structured intensity within the LG beam, thus generating a structured intensity with multilobe and multiring patterns.
View Article and Find Full Text PDFNanoscale
January 2025
Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Giuseppe Moruzzi 13, 56124 Pisa, Italy.
The development of chiral organic materials with strong non-reciprocal chiroptical features may have major implications for cutting-edge technological applications. In this work, a new synthesized chiral 1,4-diketo-3,6-dithienylpyrrolo[3,4-]pyrrole dye, bearing two ()-3,7-dimethyl-1-octyl alkyl chains on the lactam moieties and functionalized with two lateral 9-anthracenyl π-conjugated units, exhibited strong non-reciprocal chiroptical properties in thin films, with some important differences between samples prepared by drop casting and spin coating. A detailed study was performed to unravel the intimate structure-property relationship, involving computational analysis, different microscopy techniques and synchrotron radiation Mueller matrix polarimetry imaging (SR-MMP) investigation.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea.
Light metal-based nanomaterials are widely used for energy storage due to their high energy density and surface-to-volume ratio. However, their high reactivity is paradoxically both the source of advantageous properties and a hurdle to the fabrication of stable nanostructures. Here, we demonstrate the formation of nanoporous Mg via chemical redox agent-driven dealloying, which ensures minimized surface passivation and results in fine nanostructures with <50 nm of interconnected metallic ligament despite the labile chemical properties of Mg.
View Article and Find Full Text PDFJ Appl Crystallogr
January 2024
NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland, USA.
Neutron reflectometry (NR) is a powerful technique for interrogating the structure of thin films at interfaces. Because NR measurements are slow and instrument availability is limited, measurement efficiency is paramount. One approach to improving measurement efficiency is active learning (AL), in which the next measurement configurations are selected on the basis of information gained from the partial data collected so far.
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