The mechanical properties and microstructure of as-cast and homogenized AA7075 were investigated. This alloy was modified by adding transition elements 0.3%Sc + 0.5%Zr, 1%Ti + 0.2%B, and 1%Fe + 1%Ni for use in additive manufacturing applications. After adding Ti + B and Sc + Zr, the structure became uniform and finer with the formation of the Al(Sc, Zr) and TiB phases. Coarse structures were obtained with the formation of an extremely unfavorable morphology, close to a needle-like structure when Fe + Ni was added. The mechanical properties of the modified alloys were increased compared to those of the standard alloy, where the best ultimate tensile strength (UTS) and yield strength (YS) were obtained in the AA7075-TiB alloy compared to the standard alloy in as-cast and homogenized conditions, and the highest hardness value was provided by Fe + Ni additives. The effect of the laser melting process on the microstructure and mechanical properties was investigated. Single laser melts were performed on these alloys using 330 V and a scanning speed of 8 mm/s. During the laser melting, the liquation of the alloying elements occurred due to non-equilibrium solidification. A change in the microstructures was observed within the melt zone and heat-affected zone (HAZ). The hardness of the laser-melted zone (LMZ) after adding the modification elements was increased in comparison with that of the standard alloy. Corrosion testing was performed using a solution of 100 mL distilled water, 3.1 g NaCl, and 1 mL HCl over 5, 10, and 30 min and 1 and 2 h. The corrosion resistance of the alloy modified with FeNi was low because of the non-uniform elemental distribution along the LMZ, but in the case of modification with ScZr and TiB, the corrosion resistance was better compared to that of the standard alloy.
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http://dx.doi.org/10.3390/ma12203430 | DOI Listing |
J Phys Chem Lett
January 2025
Department of Physics, Indian Institute of Technology Delhi (IITD), Delhi 110016, India.
The oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are considered to be the most important processes in metal-air batteries and regenerative fuel cell devices. Metal-organic polymers are attracting interest as promising precursors of advanced metal/carbon electrocatalysts because of their hierarchical porous structure along with the integrated metal-carbon framework. We developed carbon-coated CNTs with Ni/Fe and Cu/Fe as active sites.
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January 2025
Gulliver, CNRS, ESPCI Paris, Université PSL, Paris 75005, France.
We experimentally study the formation of surface patterns in grafted hydrogel films of nanometer-to-micrometer thickness during imbibition-driven swelling followed by evaporation-driven shrinking. Creases are known to form at the hydrogel surface during swelling; the wavelength of the creasing pattern is proportional to the initial thickness of the hydrogel film with a logarithmic correction that depends on microscopic properties of the hydrogel. We find that, although the characteristic wavelength of the pattern is determined during swelling, the surface morphology can be significantly influenced by evaporation-induced shrinking.
View Article and Find Full Text PDFSci Adv
January 2025
Multiscale Bio-inspired Technology Lab, Department of Mechanical Engineering, Ajou University, 206 World cup-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do 16499, South Korea.
Highly packable and deployable electronics offer a variety of advantages in electronics and robotics by facilitating spatial efficiency. These electronics must endure extreme folding during packaging and tension to maintain a rigid structure in the deployment state. Here, we present foldable and robustly deployable electronics inspired by Plantago, characterized by their tolerance to folding and tension due to integration of tough veins within thin leaf.
View Article and Find Full Text PDFPLoS One
January 2025
School of Mechanics and Engineering, Liaoning Technical University, Fuxin, Liaoning, China.
Using the Ordos Basin dry sandstone and sandstone saturated with different saline concentrations as research subjects, a self-developed constant temperature and pressure CO2 injection simulation device was employed to conduct permeability tests on sandstone under varying effective stresses and CO2 injection pressures. The test results indicated that during the CO2 injection process, the permeability of dry sandstone was two orders of magnitude higher than that of sandstones saturated with different saline concentrations. When the effective stress increases from 10 MPa to 28 MPa, the fissure compressibility of reservoir sandstone is influenced by the saturation of different saline concentrations, with the compressibility coefficients for 0%, 15%, and 30% saline-saturated sandstone being 0.
View Article and Find Full Text PDFChem Asian J
January 2025
Kyoto Institute of Technology: Kyoto Kogei Sen'i Daigaku, Faculty of Molecular Chemistry and Engineering, Goshokaido-cho, Matsugasaki, Sakyo-ku, 606-0962, Kyoto, JAPAN.
Heteroarene-fused heteroles have attracted considerable attention owing to their unique electronic and photophysical properties. The bridging element plays a crucial role in determining the electronic characteristics of the resulting π-conjugated molecules. In this study, we synthesized a series of heteroarene-fused benzo[b]arsoles and investigated their structures and photophysical properties.
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