In this work, the qualitative analysis has been performed by using ratio of coherent to backscattering intensity ratios. The samples in the mean atomic number range 4.268≤Z‾≤5.786 and 9.743≤Z‾≤83.00 were prepared by using dilution technique. 59.54 and 661.62 keV photon energies are obtained from the radioactive point sources of Am and Cs an activity of 0.43-0.20 MBq, respectively. The scattered gamma rays were counted by a HPGe detector with a resolution of 182 eV at 5.9 keV. The obtained intensity ratios are plotted as function of the mean atomic number and constituted a best-fit-curve. The correlation coefficients for the prepared samples in the mean atomic number range 4.268≤Z‾≤5.786 are 0.976 and 0.970 at 59.54 and 661.62 keV photons, respectively. The correlation coefficients for the prepared samples in the mean atomic number range 9.743≤Z‾≤83.00 are 0.964 and 0.967 at 59.54 and 661.62 keV photons, respectively. It is observed that there was a high correlation between coherent to backscattering intensity ratio and the mean atomic numbers. It was concluded that the recommended intensity ratio can be used for qualitative analysis.
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http://dx.doi.org/10.1016/j.apradiso.2019.108926 | DOI Listing |
Sci Rep
January 2025
Institut de Recherche en Astrophysique et Planétologie, UPS/CNRS/CNES, F-31400, Toulouse, France.
The radioactive gas radon-222, a fluid and aerosol tracer in Earth's lithosphere and atmosphere, can also reveal subtle rock physics processes in extraterrestrial environments, such as those involving water, but remains poorly constrained in planetary bodies due to the limited number of samples available. Here we measure the effective radium-226 concentration (EC) of six Martian and nine lunar meteorites to derive radon source terms for Martian and lunar rocks. EC values are 0.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Chemistry, University of Bath, Bath, BA2 7AY, UK.
Copper is ubiquitous as a structural material, and as a reagent in (bio)chemical transformations. A vast number of chemical reactions rely on the near-inevitable preference of copper for positive oxidation states to make useful compounds. Here we show this electronic paradigm can be subverted in a stable compound with a copper-magnesium bond, which conforms to the formal oxidation state of Cu(-I).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Leibniz-Institut fur Festkorper- und Werkstoffforschung Dresden eV, Helmholtzstraße 20, 01069, Dresden, GERMANY.
This study presents the first successful demonstration of growing elemental bismuth (Bi) thin films via thermal atomic layer deposition (ALD) using Bi(NMe2)3 as the precursor and Sb(SiMe3)3 as the co-reactant. The films were deposited at a relatively low temperature of 100 °C, with a growth per cycle (GPC) of 0.31-0.
View Article and Find Full Text PDFInorg Chem
January 2025
Department of Chemistry, University of Alberta, Edmonton, Alberta T6G 2G2, Canada.
The lanthanide contraction is a widely known phenomenon in which the ionic radii of the Ln ions decrease across the series from La to Lu. As a result, the distance (Ln-Y), where Y is a ligand donor atom, decreases across the series. As shown previously, the decrease normally has a linear dependence on the number of 4f Ln electrons, , and the net change, Δ', is between 0.
View Article and Find Full Text PDFDalton Trans
January 2025
P.N. Lebedev Physical Institute of the Russian Academy of Sciences, Leninsky Prospekt 53, 119991 Moscow, Russian Federation.
We synthesized and investigated a new series of Sm 1,3-diketonate complexes with CF-homologous thiophene-containing ligands. A clear correlation was found between the number of fluorine atoms in the 1,3-diketone's carbon chain and the luminescent properties of the samarium(III) complexes. The ligand modification method employed facilitates targeted and significant enhancements in the photoluminescence quantum yield (PLQY).
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