We present systematic numerical simulations to understand the behavior of colloidal swimmers near a wall. We extend previous theoretical calculations based on lubrication theory to include walls with arbitrary curvature, and show how to extract from simulations a set of parameters crucial to accurately estimate the leading hydrodynamic contributions associated with the curvature of a wall. Our results show explicitly how introducing curvature to the wall not only affects the average incident angle the swimmer acquires when swimming near it, but it also leads to much broader angular distributions. This suggests an increasingly leading role of thermal fluctuations with curvature, which in turn results in significantly different motility of the swimmers. We also show how the backwards motion previously reported for pushers also extends to puller-like swimmers under the appropriate conditions. Finally, aiming at understanding the behavior of colloidal swimmers near a colloidal crystal, we also considered the case of a wall built from colloidal particles that are either free to rotate, representing a crystal held together by isotropic forces, or have their rotational degrees of freedom locked-in, representing a crystal held together by directional interactions. In both cases, we find that puller-like swimmers follow a stochastic run-and-tumble-like dynamics.
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http://dx.doi.org/10.1039/c9sm01432b | DOI Listing |
Materials (Basel)
October 2024
School of Life Science, Huaiyin Normal University, Huai'an 223300, China.
Soft Matter
October 2024
Department of Chemistry, 231 S. 34 Street, Philadelphia, PA 19104, USA.
Frustules, or the silica based cell walls of diatomaceous algae , provide large numbers of reliably cylindrical microstructures with an inner cavity and surface chemistry suitable for constructing bubble-based, acoustically-powered micro-swimmers. In this way, microswimmers can be made in a scalable, accessible and low-cost manner, enabling studies of their individual and collective behavior as active colloids.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
Department of Applied Mechanics and Biomedical Engineering, Indian Institute of Technology Madras, Chennai 600036, India; Centre for Soft and Biological Matter, Indian Institute of Technology Madras, Chennai 600036, India. Electronic address:
Hypothesis: Synthetic micro/nanomotors are gaining extensive attention for various biomedical applications (especially in drug delivery) due to their ability to mimic the motion of biological micro/nanoscale swimmers. The feasibility of these applications relies on tight control of propulsion speed, direction, and type of motion (translation, circular, etc.) along with the exerted self-propulsive force.
View Article and Find Full Text PDFNanoscale
August 2024
Institute of Inorganic Chemistry, Leibniz Universität Hannover, Callinstrasse 9, D-30167 Hannover, Germany.
Unlike conventional colloids showing random mobility because of Brownian motion, active colloids contain nanomotors that translate chemical or physical triggers into directed movement. Whereas the acceleration of such particles works well, it is difficult to decelerate them by request. Compared to the existing literature on microscaled swimmers/robots, the main question of the current paper is whether nanoscaled colloids (<100 nm) can also be actively controlled despite the stronger relevance of rotational diffusion at such dimensions.
View Article and Find Full Text PDFSoft Matter
July 2024
Department of Chemical and Biomolecular Engineering, University of Pennsylvania, Philadelphia, PA 19104, USA.
The behavior of fluid interfaces far from equilibrium plays central roles in nature and in industry. Active swimmers trapped at interfaces can alter transport at fluid boundaries with far reaching implications. Swimmers can become trapped at interfaces in diverse configurations and swim persistently in these surface adhered states.
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