Supramolecular chirality of coordination polymers of Ag with a chiral thiol ligand that bears a β-turn structure.

Chem Commun (Camb)

Department of Chemistry, College of Chemistry and Chemical Engineering, the MOE Key Laboratory of Spectrochemical Analysis and Instrumentation and iChEM, Xiamen University, Xiamen 361005, China.

Published: November 2019

AI Article Synopsis

  • The study focuses on coordination polymers made from silver (Ag) and a chiral thiol ligand with a specific β-turn structure.
  • These polymers demonstrate supramolecular chirality, meaning they have a unique handedness or orientation on a larger scale.
  • The researchers observed two effects in the system: the majority rules effect (MRE) and the racemate rules effect (RRE), which influence how these chiral structures form and behave.

Article Abstract

We report coordination polymers forming from Ag and a chiral thiol ligand that bears a β-turn structure, exhibiting supramolecular chirality showing both the majority rules effect (MRE) and the racemate rules effect (RRE).

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Source
http://dx.doi.org/10.1039/c9cc07590aDOI Listing

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