The first examples of half-sandwich Rh(i) complexes stabilized by borane coordination have been prepared and structurally characterized. As substantiated by NMR spectroscopy and single-crystal X-ray diffraction, the phosphine-borane ligand iPrP-(o-CH)-BFxyl 1 [Fxyl = 3,5-(FC)CH] engages in tight η-BCC or η-B coordination, depending on the metal environment.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c9cc06639j | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Strong metal-borane interactions in low-valent cyclopentadienyl rhodium complexes.
Chem Commun (Camb)
November 2019
CNRS/Université Paul Sabatier, Laboratoire Hétérochimie Fondamentale et Appliquée (LHFA, UMR 5069), 118 Route de Narbonne, 31062 Toulouse Cedex 09, France.
The first examples of half-sandwich Rh(i) complexes stabilized by borane coordination have been prepared and structurally characterized. As substantiated by NMR spectroscopy and single-crystal X-ray diffraction, the phosphine-borane ligand iPrP-(o-CH)-BFxyl 1 [Fxyl = 3,5-(FC)CH] engages in tight η-BCC or η-B coordination, depending on the metal environment.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!