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Vapor-Phase Linker Exchange of the Metal-Organic Framework ZIF-8: A Solvent-Free Approach to Post-synthetic Modification. | LitMetric

Zeolitic imidazolate frameworks (ZIFs) are a sub-class of metal-organic frameworks (MOFs). Although generally stable, ZIFs can undergo post-synthetic linker exchange (PSLE) in solution under mild conditions. Herein, we present a novel, solvent-free approach to post-synthetic linker exchange through exposure to linker vapor.

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http://dx.doi.org/10.1002/anie.201912088DOI Listing

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