A series of bis-[3]ferrocenophanes of the general type Fe(CHE')E-E(E'CH)Fe (E=P, SiH and E'=PBu, NPentyl, NSi(CH)) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X-ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6769432 | PMC |
| http://dx.doi.org/10.1002/open.201900182 | DOI Listing |
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