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Hydrostibination. | LitMetric

Hydrostibination.

Angew Chem Int Ed Engl

Chemistry Department, Dalhousie University, 6274 Coburg Road, Halifax, Nova Scotia, Canada.

Published: December 2019

AI Article Synopsis

Article Abstract

A rigid naphthalenediamine framework has been used to prepare antimony hydrides that feature LUMO shapes and energies similar to those found in secondary boranes. By exploiting this feature, we introduce the first examples of uncatalyzed hydrostibination reactions of robust C≡C, C=C, C=O, and N=N bonds as new elementary hydrometalation reactions analogous to hydroboration. These results endorse the notion of a diagonal relationship between the lightest p-block element and the heaviest Group 15 elements and may lead to the conception of novel reaction chemistry.

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Source
http://dx.doi.org/10.1002/anie.201911842DOI Listing

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Hydrostibination.

Angew Chem Int Ed Engl

December 2019

Chemistry Department, Dalhousie University, 6274 Coburg Road, Halifax, Nova Scotia, Canada.

A rigid naphthalenediamine framework has been used to prepare antimony hydrides that feature LUMO shapes and energies similar to those found in secondary boranes. By exploiting this feature, we introduce the first examples of uncatalyzed hydrostibination reactions of robust C≡C, C=C, C=O, and N=N bonds as new elementary hydrometalation reactions analogous to hydroboration. These results endorse the notion of a diagonal relationship between the lightest p-block element and the heaviest Group 15 elements and may lead to the conception of novel reaction chemistry.

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