A novel flexible ion-selective sensor for potassium and sodium detection was proposed. Flexible ion-selective electrodes with pseudo-liquid internal solution on contrary to the system with a solid contact provided a more stable analytical signal. Such advantages were achieved because of polyelectrolyte (PEI/PSS) layers adsorption on the conduct substrate with a layer-by-layer technique. Such an approach demonstrated that ion-selective electrodes save sensitivity with Nernstian dependence: 56.2 ± 1.4 mV/dec and 56.3 ± 1.9 mV/dec , as well as a fast time of response for potassium (5 s) and sodium (8 s) was shown. The sensing platform proposed demonstrates a better time of response and is close to the Nernstian value of sensitivity with a sensor low cost. The results proposed confirm a pseudo-liquid junction for the ion-selective electrode. Biocompatibility of an ion-selective sensing platform was demonstrated at potassium potentiometric measurements in biofilms. Potassium levels in a biofilm were measured with potentiometry and showed agreement with the previous results.
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http://dx.doi.org/10.1021/acsomega.9b01464 | DOI Listing |
Nanomicro Lett
December 2024
School of Microelectronics, Southern University of Science and Technology, Shenzhen, 518055, People's Republic of China.
Ammonium level in body fluids serves as one of the critical biomarkers for healthcare, especially those relative to liver diseases. The continuous and real-time monitoring in both invasive and non-invasive manners is highly desired, while the ammonium concentrations vary largely in different body fluids. Besides, the sensing reliability based on ion-selective biosensors can be significantly interfered by potassium ions.
View Article and Find Full Text PDFTalanta
November 2024
Graduate School of Biomedical Engineering, Tohoku University, Sendai, Miyagi, 980-8579, Japan; Frontier Research Institute for Interdisciplinary Sciences (FRIS), Tohoku University, Sendai, Miyagi, 980-0845, Japan. Electronic address:
The monitoring of ion homeostasis in vivo is of paramount importance due to its critical functions in biological systems. However, current leading technologies for creating ion-selective electrodes often fall short of the requirements for in vivo applications in terms of multiplexity, miniaturization, and flexibility. To address this gap, we introduce an integrated multiplexed ion monitoring probe created from thermally drawn multi-electrode polymer fiber, aimed at enhancing in vivo ion homeostasis studies.
View Article and Find Full Text PDFSci Bull (Beijing)
October 2023
Guangdong Engineering Technology Research Center for Photoelectric Sensing Materials & Devices, Guangzhou Key Laboratory of Sensing Materials & Devices, Center for Advanced Analytical Science, School of Chemistry and Chemical Engineering, School of Economics and Statistics, Guangzhou University, Guangzhou 510006, China; School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, China. Electronic address:
Noninvasive and continuous monitoring of electrolytes in biofluids based on wearable biotechnology provides extensive health-related physiological information. The state-of-the-art wearable bioelectronic ion sensors depend on the organic ionophore-based solid-contact structure of potentiometric ion-selective electrodes. This structure contains two functional sensing layers, i.
View Article and Find Full Text PDFDalton Trans
October 2024
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow 119071, Russia.
Phosphoryl podands of neutral type with a flexible ethylene glycol chain and diphenylphosphorylmethyl end groups are known for their complexation properties towards various cations. In this work, the complexation process between 1,3-bis(diphenylphosphoryl)-2-oxapropane (L) and lanthanide ions was studied. Namely, the stability constants of lanthanide complexes with L in acetonitrile were estimated by the method of spectrophotometric titration.
View Article and Find Full Text PDFAnal Sci
December 2024
Department of Chemistry, St. Joseph's College (Autonomous), Devagiri, Affiliated to University of Calicut, Calicut, 673008, Kerala, India.
Despite the fact that there are already a number of solid-contact-based ion-selective electrodes designed for atrazine detection, our ground-breaking contribution lies in introducing the first-ever atrazine potentioselectrode, enabling the ultra-sensitive detection of atrazine at nanomolar levels. Solid-contact ion-selective electrodes can offer advantages, such as improved stability, reproducibility, sensitivity, and selectivity compared to their liquid-contact counterparts. Here, a biomimetic potentiometric sensor for Atrazine was developed using economic, light weight, and flexible carbon cloth as solid-contact material.
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