A dislocation induces ferroelectricity around it in incipient ferroelectric SrTiO3 due to some reasons such as electro-mechanical coupling and it being a one-dimensional ferroelectric nanostructure. Furthermore, this microstructure is arrayed periodically in the material and dislocation structures such as a dislocation wall are formed. Due to these facts, periodically-arrayed ferroelectric nanostructures, which show various intriguing polarization configurations and functionalities depending on the internal periodic structure, may be fabricated by dislocations. The phase-field simulation exhibits that a ferroelectric nano-region induced by the strain concentration and incidental electric field around a dislocation connects with each other in a dislocation wall. As a result, a periodic ferroelectric nano-region, which is a periodically-arrayed ferroelectric nanostructure embedded in paraelectric matrices, is formed. Our findings provide a new pathway for the fabrication of novel functional nanodevices in ferroelectric systems.
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http://dx.doi.org/10.1039/c9cp04147h | DOI Listing |
Nanoscale
November 2019
State Key Lab of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China.
Ferroelectric topological configurations confined in nanostructures have attracted intensive interest both in fundamental physics and potential applications in non-volatile nanoelectronic devices. However, the preparation approaches such as chemical synthesis and template or electron beam etching inevitably induce damage and contamination; also, these are complicated processes. Herein, by a delicate design of the wetting layer and growth temperature, self-assembled ferroelectric nanoislands were achieved with the BiFeO/(La,Sr)MnO/LaAlO heterostructure.
View Article and Find Full Text PDFPhys Chem Chem Phys
October 2019
Department of Mechanical Engineering and Science, Kyoto University, Nishikyo-ku, Kyoto 615-8540, Japan.
Ferroelectric materials exhibit novel topological polarization configurations due to geometric confinements originating from the material shapes and interfaces at the nanoscale. In this study, we demonstrate that those nontrivial topological ferroelectric nanostructures can be tailored in paraelectric nanoporous materials by mechanical loads using phase-field modeling. That is, in nanoporous strontium titanate, periodically-arrayed ferroelectric nanostructures in the shape of networks are formed due to strain concentrations by mechanical loads, and topological polarization configurations, such as hierarchical vortices, woven fabrics and nested structures of spiral like Hopf fibration, are stabilized in the structures strongly affected by the pore arrangements.
View Article and Find Full Text PDFPhys Chem Chem Phys
October 2019
Department of Mechanical Engineering and Science, Kyoto University, Nishikyo-ku, Kyoto 615-8540, Japan.
A dislocation induces ferroelectricity around it in incipient ferroelectric SrTiO3 due to some reasons such as electro-mechanical coupling and it being a one-dimensional ferroelectric nanostructure. Furthermore, this microstructure is arrayed periodically in the material and dislocation structures such as a dislocation wall are formed. Due to these facts, periodically-arrayed ferroelectric nanostructures, which show various intriguing polarization configurations and functionalities depending on the internal periodic structure, may be fabricated by dislocations.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!